DIELECTRIC RELAXATION OF DIHYDRIC ALCOHOL-1,4-DIOXANE MIXTURES USING TIME DOMAIN TECHNIQUE

被引：3
|
作者：
Shinde, M. N. [1 ]
Talware, R. B. [1 ]
Kumbharkhane, A. C. [1 ]
机构：
[1] Swami Ramanand Teerth Marathwada Univ, Sch Phys Sci, Nanded 431606, Maharashtra, India
来源：
LITHUANIAN JOURNAL OF PHYSICS | 2011年 / 51卷 / 01期
关键词：
dielectric relaxation; time domain reflectometry; alcohols; ALCOHOL-WATER MIXTURES; PLUS LIQUID EQUILIBRIUM; TEMPERATURE; 313.15; K; BINARY-MIXTURES; DYNAMICAL STRUCTURES; REFRACTIVE-INDEXES; BEHAVIOR; N; N-DIMETHYLACETAMIDE; CONSTANTS; VISCOSITY;
D O I：
10.3952/lithjphys.51102
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
Complex dielectric permittivity measurements of 1,2-propanediol-1,4-dioxane mixtures has been carried out at different concentration and in the frequency range of 10 MHz to 20 GHz using time domain reflectometry (TDR). The least squares fit method has been used to obtain the static dielectric constant, relaxation time, and Bruggeman factor for binary mixtures. The Kirkwood-Frohlich theory is applied to compute the dielectric constant for the mixtures. It adequately reproduces the experimental values of static dielectric constants for the 1,2-propanediol-dioxane mixtures. The excess parameters confirm that the heteromolecular hydrogen bonding interactions between 1,2-propanediol and dioxane molecules vary significantly in the mixture. The Bruggeman model for the nonlinear case has been fitted to the experimental dielectric data for mixtures.
引用
收藏
页码：39 / 45
页数：7
相关论文
共 50 条
  • [1] Structural Behavior of Alcohol-1,4-Dioxane Mixtures through Dielectric Properties Using TDR
    Kumbharkhane, Ashok C.
    Shinde, M. N.
    Mehrotra, Suresh C.
    Oshiki, Noriaki
    Shinyashiki, Naoki
    Yagihara, Shin
    Sudo, Seiichi
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (38): : 10196 - 10201
  • [2] Dielectric study of acrylonitrile-1,4-dioxane mixtures using a Time Domain Reflectometry
    Dongre, D. G.
    Gubre, A. G.
    Garad, N. P.
    Saknure, S. H.
    Kumbharkhane, A. C.
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2025, 63 (01) : 13 - 21
  • [3] Dielectric relaxation of dioxane-water mixtures using time domain technique
    Kanse, KS
    Chavan, SD
    Kumbharkhane, AC
    Mehrotra, SC
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2006, 83 (02) : 168 - 171
  • [4] Dielectric relaxation study of hexamethylphosphoramide-1, 4-dioxane mixtures using time domain reflectometry (TDR) technique
    Mahajan, G. R.
    Kumbharkhane, A. C.
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2012, 50 (04) : 513 - 522
  • [5] Dielectric relaxation study of 2 and 3-chloroaniline and 2 and 3-methoxyaniline with 1,4-dioxane mixtures using time domain technique
    Kadam, S. S.
    Hudge, P. G.
    Suryawanshi, D. B.
    Kumbharkhane, A. C.
    JOURNAL OF MOLECULAR LIQUIDS, 2013, 177 : 426 - 431
  • [6] High Frequency Dielectric Measurements of Alcohol-Dioxane Mixtures using a Time domain Technique
    Kumbharkhane, A. C.
    Mehrotra, S. C.
    INTERNATIONAL CONFERENCE ON RECENT ADVANCES IN MICROWAVE THEORY AND APPLICATIONS, PROCEEDINGS, 2008, : 166 - +
  • [7] Exploring dielectric relaxation in 1,2-propanediol and 1,4-dioxane binary mixtures: time-domain reflectometry analysis
    Garad, Nitin P.
    Kumbharkhane, Neha A.
    Kumbharkhane, Ashok C.
    CANADIAN JOURNAL OF CHEMISTRY, 2025, 103 (01) : 19 - 26
  • [8] Dielectric relaxation and hydrogen bonding studies of chlorobutane-dioxane mixtures using a time domain technique
    Gubre, A. G.
    Kumbharkhane, A. C.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2023, 100 (06)
  • [9] Dielectric relaxation of binary mixtures of diethylene triamine propane diol in 1,4-dioxane using microwave techniques
    Nimkar, MJ
    Pande, R
    Kalamse, GM
    ASIAN JOURNAL OF CHEMISTRY, 2005, 17 (01) : 270 - 276
  • [10] Dielectric properties of ethyleneglycol-1,4-dioxane mixtures using TDR method
    Sudo, Seiichi
    Oshiki, Noriaki
    Shinyashiki, Naoki
    Yagihara, Shin
    Kumbharkhane, Ashok C.
    Mehrotra, Suresh C.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (16): : 2993 - 2998
12345