A ratiometric fluorescent sensor for zinc(II) with high selectivity

被引:42
|
作者
Chen, Huili [1 ,2 ]
Wu, Yanbo [1 ]
Cheng, Yunfei [2 ]
Yang, Hong [2 ]
Li, Fuyou [2 ]
Yang, Pin [1 ]
Huang, Chunhui [2 ]
机构
[1] Shanxi Univ, Educ Minist, Key Lab Chem Biol & Mol Engn, Inst Mol Sci, Taiyuan 030006, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Dept Chem, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
ratiometric; fluorescence; Zn2+ sensor; schiff base;
D O I
10.1016/j.inoche.2007.08.028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Spectroscopic studies revealed that the compound [N,N'-di(quinoline-2-methylene)-1,2-phenylenediimine] (1) exhibited a rather high selectivity toward Zn2+ over other metal ions, even Cd2+. In acetonitrile, the red shift of fluorescent emission from 396 nm to 426 nm upon zinc binding is due to the formation of a 1:1 metal/ligand complex. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1413 / 1415
页数:3
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