Densities and excess molar volumes of the ternary mixture (1-butanol plus n-hexane plus 1-chlorobutane) at 298.15 and 313.15 K. Application of the ERAS model

被引:14
|
作者
Dominguez, M [1 ]
Artigas, H [1 ]
Santafe, J [1 ]
Mainar, A [1 ]
Urieta, JS [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, Area Quim Fis,Secc Quim, E-50009 Zaragoza, Spain
关键词
densities; excess volumes; mixture; ERAS model; 1-butanol; n-hexane; 1-chlorobutane;
D O I
10.1016/S0378-3812(97)00293-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities of the liquid mixtures (n-hexane + 1-chlorobutane) and (1-butanol + n-hexane + 1-chlorobutane) have been measured by the vibrating tube technique at 298.15 K and 313.15 K. With these densities, excess molar volumes were calculated. An extended version of the so-called ERAS model has been used for describing VE Of the complete ternary system at 298.15 K. Qualitatively the ERAS-model gives an adequate representation of this system, being similar the shapes of both the experimental and the predicted curves. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:115 / 128
页数:14
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