Time-of-flight secondary-ion-mass spectrometric (ToF-SIMS) and X-ray photoelectron spectroscopic (XPS) analyses of the surface lipids of wool

被引:15
|
作者
Shao, J [1 ]
Jones, DC
Mitchell, R
Vickerman, JC
Carr, CM
机构
[1] Univ Manchester, Inst Sci & Technol, Dept Text, Manchester 1, Lancs, England
[2] Univ Manchester, Inst Sci & Technol, Dept Chem, Manchester 1, Lancs, England
[3] CSMA Ltd, Manchester 1, Lancs, England
关键词
D O I
10.1080/00405000.1997.11090886
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
ToF-SIMS studies of wool show the presence of lipid material at the surface epicuticle layer. The major lipid component is a C-21-fatty acid linked to the wool protein via a thioester linkage. This C-21-fatty-acid species is sensitive to chemical attack and is removed/modified by aqueous chlorination and plasma treatment but is relatively unaffected by permonosulphuric acid (PMS)/sulphite treatment, XPS confirms that less sulphur oxidation occurs with PMS/sulphite treatment than with aqueous chlorination.
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页码:317 / 324
页数:8
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