A facile and efficient stereoselective synthesis of highly functionalized trisubstituted alkene derivatives of ferrocenealdehyde

被引：19
|
作者：
Shanmugam, Ponnusamy [1 ]
Vaithiyanathan, Vadivel [1 ]
Viswambharan, Baby [1 ]
Madhavan, Suchithra [1 ]
机构：
[1] Natl Inst Interdisciplinary Sci & Technol, Chem Sci & Technol Div, Thiruvananthapuram 695019, Kerala, India
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 52期
关键词：
ferrocenealdehyde; Baylis-Hillman adduct; trisubstituted;
D O I：
10.1016/j.tetlet.2007.10.103
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of the Baylis-Hillman adduct 2 of ferrocenealdehyde with various oxygen and carbon nucleophiles in the presence of montmorillonite K10 clay catalyst furnished highly functionalised trisubstituted alkene derivatives of ferrocenealdehyde in excellent yield. Synthetic use of one of products 7 has been demonstrated with the synthesis of a 1,3-diyne ether derivative of ferrocene 16 via an Eglinton coupling reaction. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9190 / 9194
页数：5
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