Weak C-H•••Cl-Pd interactions toward conformational polymorphism in trans-dichloridobis(triphenylphosphane)palladium(II)

被引：14

作者：

Correa, Rodrigo S. ^{[1
]}

Graminha, Angelica E. ^{[1
]}

Ellena, Javier ^{[2
]}

Batista, Alzir A. ^{[1
]}

机构：

[1] Univ Fed Sao Carlos UFSCar, Dept Quim, BR-13561901 Sao Carlos, SP, Brazil

[2] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2011年 / 67卷

关键词：

TRANS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II); PALLADIUM(II);

D O I：

10.1107/S0108270111033051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new triclinic polymorph of the title compound, [PdCl2(C18H15P)(2)], has two independent molecules in the unit cell, with the Pd atoms located on inversion centres. One molecule has an eclipsed conformation, whereas the second molecule adopts a gauche conformation. The molecules with a gauche conformation are involved in weak intermolecular C-H center dot center dot center dot Cl-Pd interactions with symmetry-related molecules. It is suggested that C-H center dot center dot center dot Cl-Pd interactions are mainly responsible for the existence of conformational differences, which contribute to the polymorph formation. In the crystal, there are layers of eclipsed and gauche molecules separated by normal van der Waals interactions.

引用

页码：M304 / M306

页数：3

共 50 条

[1] trans-Dichloridobis(triphenylphosphane-kappa P)palladium(II) benzene hemisolvate
Meyer-Wegner, Frank
Lerner, Hans-Wolfram
Sinke, Tanja
Bolte, Michael
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M507 - +
[2] Crystal structure of trans-dichloridobis(isoquinoline-κN)palladium(II), C18H14Cl2N2Pd
Ha, Kwang
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2014, 229 (02): : 153 - 154
[3] 2D and 3D supramolecular assemblies of double cyclopalladated azobenzenes realized by C-H•••Cl-Pd, π•••π and C-H•••π interactions
Molcanov, Kresimir
Curic, Manda
Babic, Darko
Kojic-Prodic, Biserka
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (18) : 3874 - 3881
[4] Effect of C-H ••• S and C-H ••• Cl interactions on the conformational preference of inhibitors of TIBO family
Freitas, Renato F.
Galembeck, Sergio E.
CHEMICAL PHYSICS LETTERS, 2006, 423 (1-3) : 131 - 137
[5] Concomitant polymorphism in 3-acetylcoumarin:: Role of weak C-H•••O and C-H•••π interactions
Munshi, P
Venugopala, KN
Jayashree, BS
Row, TNG
CRYSTAL GROWTH & DESIGN, 2004, 4 (06) : 1105 - 1107
[6] Weak intramolecular C-H•••H-B and C-H•••Cl interactions in C-aminoboryl-o-carboranes
Nie, Yong
Miao, Jinling
Pritzkow, Hans
Wadepohl, Hubert
Siebert, Walter
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 747 : 174 - 177
[7] An X-ray powder study of the structure and microstructure of trans-dichloridobis(1,5-diamino-1H-tetrazole-κN4)palladium(II)
Ivashkevich, Ludmila S.
Lyakhov, Alexander S.
Serebryanskaya, Tatiyana V.
Gaponik, Pavel N.
Ivashkevich, Oleg A.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2012, 227 (10): : 702 - 709
[8] Supramolecular assemblies of cis-palladium complexes dominated by C-H•••Cl interactions
Moro, A. C.
Watanabe, F. W.
Ananias, S. R.
Mauro, A. E.
Netto, A. V. G.
Lima, A. P. R.
Ferreira, J. G.
Santos, R. H. A.
INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (05) : 493 - 496
[9] Coordination geometry isomerism induced by N-H•••Cl, C-H•••Cl, C-H•••N, C-H•••π and π•••π supramolecular interactions in mercury(II) complexes with tripyridylimidazole chelating ligands
Campos-Gaxiola, Jose J.
Hopfl, Herbert
Parra-Hake, Miguel
INORGANICA CHIMICA ACTA, 2008, 361 (01) : 248 - 254
[10] Pd-N-H•••Cl-Pd hydrogen bonds and π-π interactions between fluorinated aromatic rings in trans-[PdCl2(NH2ArF)2]
Baldovino-Pantaleon, Oscar
Morales-Morales, David
Hernandez-Ortgega, Simon
Toscano, Ruben A.
Valdes-Martinez, Jesus
CRYSTAL GROWTH & DESIGN, 2007, 7 (01) : 117 - 123

← 1 2 3 4 5 →