Comment on "Correlations between isobaric and isochoric fragilities and thermodynamical scaling exponent for glass-forming liquids"

被引:3
|
作者
Casalini, R. [1 ]
Roland, C. M.
机构
[1] George Mason Univ, Dept Chem, Fairfax, VA 22030 USA
[2] USN, Res Lab, Washington, DC 20375 USA
[3] USN, Res Lab, Div Chem, Washington, DC 20375 USA
来源
PHYSICAL REVIEW E | 2007年 / 76卷 / 01期
关键词
D O I
10.1103/PhysRevE.76.013501
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
For nonassociated, glass-forming liquids and polymers, thermodynamic scaling of structural relaxation times and viscosities is an empirical fact, demonstrated by various groups for dozens of materials. The P and T invariance of the isochoric fragility follows directly from this scaling. Apparent inconsistencies with these statements were reported recently by Grzybowski [A. Grzybowski, K. Grzybowska, J. Ziolo, and M. Paluch, Phys. Rev. E 74, 041503 (2006)]; however, the putative inconsistencies arise from use at higher pressures of parameters to correlate the isobaric and isochoric fragilities that are valid only for ambient pressure.
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页数:2
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