Palladium-catalyzed selective cycloaddition of diazo compounds to [60]fullerene

被引：9
|
作者：
Tuktarov, Airat R. [1 ]
Akhmetov, Arslan R. [1 ]
Korolev, Vyacheslav V. [1 ]
Khuzin, Artur A. [1 ]
Khasanova, Liliya L. [1 ]
Popod'ko, Natal'ya R. [1 ]
Khalilov, Leonard M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prospekt Oktyabrya, Ufa 450075, Russia
来源：
ARKIVOC | 2011年
关键词：
60]Fullerene; diazo compounds; cycloaddition; metal complex catalysts; homofullerene; methanofullerene; C-60; FULLERENES; FULLEROIDS; CHEMISTRY;
D O I：
10.3998/ark.5550190.0012.804
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The effective catalytic method for cycloaddition of higher diazoalkanes and diazoacetates to [60] fullerene in the presence of the three-component catalytic system Pd(acac)(2)-PPh3-Et3Al has been developed. The yield and selective formation of the target homo- and methanofullerenes are dependent upon the structure of the original diazo compounds.
引用
收藏
页码：54 / 66
页数：13
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