Synthesis of chiral bis-thiazolines and asymmetric Diels-Alder reactions

被引:15
|
作者
Nishio, T [1 ]
Kodama, Y
Tsurumi, Y
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
[2] Univ Tsukuba, Grad Sch Environm Sci, Tsukuba, Ibaraki 3058571, Japan
关键词
asymmetric catalyst; bis-(N-acylamino) alcohol; chiral bis-thiazoline; Diels-Alder reaction; Lawesson's reagent;
D O I
10.1080/10426500590913032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New chiral ligands, bis-thiazoline derivatives (sulfur analogues of known oxazolines) were prepared from chiral bis-(N-acylamino alcohols) with Lawesson's reagent. Bis-thiazolines thus obtained proved to be useful chiral ligands for metal in asymmetric Diels-Alder reaction.
引用
收藏
页码:1449 / 1450
页数:2
相关论文
共 50 条
  • [1] ASYMMETRIC DIELS-ALDER REACTIONS WITH CHIRAL ALKOXYCYCLOHEXADIENES
    BIRD, CW
    LEWIS, A
    TETRAHEDRON LETTERS, 1989, 30 (45) : 6227 - 6228
  • [2] Asymmetric Diels-Alder reactions of cyclopentadiene in the synthesis of chiral norbornene derivatives
    Mamedov, E. G.
    Klabunovskii, E. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (08) : 1097 - 1120
  • [3] Asymmetric Diels-Alder reactions of cyclopentadiene in the synthesis of chiral norbornene derivatives
    E. G. Mamedov
    E. I. Klabunovskii
    Russian Journal of Organic Chemistry, 2008, 44 : 1097 - 1120
  • [4] Chiral anthracenes as a Diels-Alder/retro Diels-Alder template in asymmetric synthesis.
    Sanyal, A
    Snyder, JK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U121 - U121
  • [5] A CHIRAL ACYCLIC BIS-ALLYLIC COMPOUND AS A DIENOPHILE FOR ASYMMETRIC DIELS-ALDER REACTIONS
    SAITO, S
    HAMA, H
    MATSUURA, Y
    OKADA, K
    MORIWAKE, T
    SYNLETT, 1991, (11) : 819 - 820
  • [6] Organocatalytic asymmetric Diels-Alder reactions with novel chiral hydrazines
    Cook, Gregory R.
    Vaughn, Danielle
    Bhor, Santosh
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [7] The sulfinyl group as a chiral inductor in asymmetric Diels-Alder reactions
    Ruano, JLG
    Carretero, JC
    Carreno, MC
    Cabrejas, LMM
    Urbano, A
    PURE AND APPLIED CHEMISTRY, 1996, 68 (04) : 925 - 930
  • [8] ASYMMETRIC DIELS-ALDER REACTIONS WITH CHIRAL 1-AZADIENES
    BEAUDEGNIES, R
    GHOSEZ, L
    TETRAHEDRON-ASYMMETRY, 1994, 5 (04) : 557 - 560
  • [9] Asymmetric Diels-Alder reactions with a diketopiperazine chiral auxiliary.
    Le, TX
    Bussolari, JC
    Gauthier, D
    Kuo, GH
    Murray, WV
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 414 - ORGN
  • [10] ASYMMETRIC DIELS-ALDER REACTIONS OF CHIRAL ALKOXY IMINIUM SALTS
    JUNG, ME
    VACCARO, WD
    BUSZEK, KR
    TETRAHEDRON LETTERS, 1989, 30 (15) : 1893 - 1896