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Valence photoelectron spectra of Na, K, Rb and Cs with s or p outermost electron:: Evolution of the states from LS-coupling to jK-coupling
被引:3
|作者:
Maeaetae, M.
Schultz, J.
Heinaesmaeki, S.
Aksela, H.
机构:
[1] Oulu Univ, Dept Phys Sci, FIN-90014 Oulu, Finland
[2] Uppsala Univ, Dept Phys, SE-75121 Uppsala, Sweden
基金:
芬兰科学院;
关键词:
alkali metals;
valence photoelectron spectrum;
pure coupling schemes;
LS-coupling;
jK-coupling;
D O I:
10.1016/j.elspec.2007.02.031
中图分类号:
O433 [光谱学];
学科分类号:
0703 ;
070302 ;
摘要:
The development of the fine structure of the np(5)(n + 1)s and np(5)(n + 1)p (n = 2 in Na, n = 3 in K, n = 4 in Rb, n = 5 in Cs) configurations of alkali atoms ions from LS-coupling to jK-coupling has been studied by comparing the experimental photoelectron spectra with the results obtained with analytical LS-coupling and jK-coupling models. (c) 2007 Elsevier B.V. All rights reserved.
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页码:99 / 104
页数:6
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