Electronic interchain interactions of the Cu(110)(2 x 1)O surface - an angle-resolved photoemission study

被引:10
|
作者
Berge, K [1 ]
Goldmann, A [1 ]
机构
[1] Univ Kassel, Fachbereich Phys, D-34132 Kassel, Germany
关键词
copper oxides; angle resolved photoemission; photoelectron spectroscopy; surface electronic phenomena (work function; surface potential; surface states; etc.);
D O I
10.1016/S0039-6028(03)00778-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using angle-resolved photoemission at homega = 21.2 eV we have measured the electronic energy band dispersion perpendicular to the Cu-O chains, i.e. along the (&UGamma;) over bar - (X) over bar and (Y) over bar - (S) over bar directions of the surface Brillouin zone. Our work treats exclusively the occupied antibonding states observed at binding energies between E-F and the upper edge of the Cu d-bands. We studied both the fully oxygen-covered surface (0.5 ML coverage) and the striped surface (global coverage <0.5 ML), where alternating Cu(1 1 0) and (2 x 1)O domains form a quasi-1D nanograting. In addition we analyze an umklapp-process of bulk substrate emission. It is induced by the (2 x 1) lattice of the adsorbate and needs to be distinguished from oxygen-derived electronic properties. We compare our results with earlier experimental studies and with available surface band structure calculations. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:97 / 106
页数:10
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