Metal bis(acetylide) complex molecular wires: concepts and design strategies

被引：52
|
作者：
Milan, David C. [1 ]
Vezzoli, Andrea [1 ]
Planje, Inco J. [1 ]
Low, Paul J. [2 ]
机构：
[1] Univ Liverpool, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England
[2] Univ Western Australia, Sch Mol Sci, 35 Stirling Highway, Crawley, WA 6009, Australia
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 40期
基金：
澳大利亚研究理事会;
关键词：
SINGLE-MOLECULE; LENGTH DEPENDENCE; CHARGE-TRANSPORT; QUANTUM-INTERFERENCE; JUNCTION CONDUCTANCE; ELECTRONICS; CHEMISTRY; TEMPERATURE; VARIABILITY; TRANSITION;
D O I：
10.1039/c8dt02103a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The past decade has seen a remarkable surge in studies of thin-film and single-molecule electronics, due in no small part to the development and advancement of experimental methods for the construction and measurement of metal|molecule|metal junctions. Within the plethora of molecular structures that have been investigated, metal complexes of general form trans-M(C?CR)(2)(L-n) have attracted attention from the inorganic and organometallic chemistry community in the search for efficient molecular wires due to the potential -d- orbital mixing along the molecular backbone. In this article progress towards this goal will be summarised, and design strategies for future molecular components discussed.
引用
收藏
页码：14125 / 14138
页数：14
相关论文
共 50 条
  • [1] π-Conjugated bis(terpyridine) metal complex molecular wires
    Sakamoto, Ryota
    Wu, Kuo-Hui
    Matsuoka, Ryota
    Maeda, Hiroaki
    Nishihara, Hiroshi
    CHEMICAL SOCIETY REVIEWS, 2015, 44 (21) : 7698 - 7714
  • [2] Synthesis of a ferrocenyl-capped ruthenium(II) bis(acetylide) complex: A model for organometallic molecular wires
    Jones, ND
    Wolf, MO
    Giaquinta, DM
    ORGANOMETALLICS, 1997, 16 (07) : 1352 - 1354
  • [3] An efficient synthesis of acetylide/trimetal/acetylide molecular wires
    Berry, JF
    Cotton, FA
    Murillo, CA
    Roberts, BK
    INORGANIC CHEMISTRY, 2004, 43 (07) : 2277 - 2283
  • [4] Insulated molecular wires: Inhibiting orthogonal contacts in metal complex
    Milan, David Costa
    Al-owaedi, Oday
    Bock, Soeren
    Oerthel, Marie
    Inkpen, Michael
    Yufit, Dmitry
    Sobolev, Alexandre
    Long, Nicholas
    Albrecht, Tim
    Higgins, Simon
    Bryce, Martin
    Nichols, Richard
    Lambert, Colin
    Low, Paul
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [5] Electron Transport Behavior Analysis of Bis(terpyridine) Metal Complex Wires on Electrodes
    Maeda, H.
    Sakamoto, R.
    Nishihara, H.
    LOW-DIMENSIONAL NANOSCALE ELECTRONIC AND PHOTONIC DEVICES 9, 2016, 75 (11): : 17 - 24
  • [6] Construction of molecular wires based on a gold(I) bis-σ-acetylide building block incorporated into ruthenium(II) polypyridyl complexes
    Shiotsuka, M
    Yamamoto, Y
    Okuno, S
    Kitou, M
    Nozaki, K
    Onaka, S
    CHEMICAL COMMUNICATIONS, 2002, (06) : 590 - 591
  • [7] Insulated molecular wires: inhibiting orthogonal contacts in metal complex based molecular junctions
    Al-Owaedi, Oday A.
    Bock, Soren
    Milan, David C.
    Oerthel, Marie-Christine
    Inkpen, Michael S.
    Yufit, Dmitry S.
    Sobolev, Alexandre N.
    Long, Nicholas J.
    Albrecht, Tim
    Higgins, Simon J.
    Bryce, Martin R.
    Nichols, Richard J.
    Lambert, Colin J.
    Low, Paul J.
    NANOSCALE, 2017, 9 (28) : 9902 - 9912
  • [8] Molecular metal wires and molecular switches
    Peng, SM
    AINA 2005: 19th International Conference on Advanced Information Networking and Applications, Vol 2, 2005, : 519 - 519
  • [9] Design Concepts for NiTiNOL Wires to Function as a Sensor
    D. Josephine Selvarani Ruth
    Transactions of the Indian National Academy of Engineering, 2021, 6 (2) : 523 - 531
  • [10] Multidecker Bis(benzene)chromium: Opportunities for Design of Rigid and Highly Flexible Molecular Wires
    Jiang, Jun
    Smith, Joshua R.
    Luo, Yi
    Grennberg, Helena
    Ottosson, Henrik
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (03): : 785 - 790
12345