Construction of a cadmium supermolecular compound from 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic acid

被引：19
|
作者：
Jing, Xuemin [1 ]
Zhao, Tingting [1 ]
Zheng, Bing [1 ]
Peng, Yu [1 ]
Yan, Yan [1 ]
Huo, Qisheng [1 ]
Liu, Yunling [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期
关键词：
Solvothermally synthesized; Hydrogen-bondings; Supermolecular; Metal-organic frameworks; METAL-ORGANIC FRAMEWORKS; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; LIGANDS; TOPOLOGY; POLYMERS; CD(II); IONS;
D O I：
10.1016/j.inoche.2010.09.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cadmium compound [Cd(C10H5N3O4)(H2O)(2)] 1, based on 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic acid (H(3)PylmDC) has been solvothermally synthesized and characterized. Single-crystal structural analysis reveals that the compound crystallizes in the orthorhombic system, Pna2(1) space group with a = 6.8293(14) angstrom, b = 12.331(3) angstrom, c = 13.732(3) angstrom, V = 1156.3(4) angstrom(3) and R-1 = 0.0257. In compound 1, two nitrogen and two oxygen atoms of the H(3)PylmDC ligand coordinate to two Cd2+ ions to form a straight chain which then pack with each other via strong pi-pi and hydrogen-bondings interactions to construct a three-dimensional (3D) supermolecular structure. Further characterization of compound 1 was performed by X-ray powder diffraction (XRD), thermal gravimetric analyses (TG). infrared (IR) spectra, inductively coupled plasma (ICP) and elemental analyses. The fluorescent property was also evaluated. (C) 2010 Elsevier B.V. All rights reserved.
引用
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页码：22 / 25
页数：4
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