Facile and Practical Synthesis of Platinum(II) Porphyrins under Mild Conditions

被引：11
|
作者：
Yamashita, Ken-ichi [1 ]
Katsumata, Natsuki [1 ]
Tomita, Shohei [1 ]
Fuwa, Miki [1 ]
Fujimaki, Keisuke [1 ]
Yoda, Takuya [1 ]
Hirano, Daisuke [1 ]
Sugiura, Ken-ichi [1 ]
机构：
[1] Tokyo Metropolitan Univ, Grad Sch Sci & Engn, Dept Chem, Hachioji, Tokyo 1920397, Japan
来源：
CHEMISTRY LETTERS | 2015年 / 44卷 / 04期
关键词：
SENSING MATERIALS; HIGHLY EFFICIENT; OXYGEN SENSOR; PHOSPHORESCENT; LUMINESCENCE; COMPLEXES; ELECTROCHEMISTRY; MICROSCOPY; DEVICES;
D O I：
10.1246/cl.141112
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile and mild method for the preparation of platinum(II) porphyrin complexes is reported. A simple treatment of free-base porphyrins with 1.5 equiv of [PtCl2(PhCN)(2)] in the presence of sodium propionate in reftwdng chlorobenzene (bp: 131 degrees C) affords the corresponding Pt(E) complexes in good yields within a few hours. Furthermore, the work-up processes for our methods are less complex than those for the reported ones because chlorobenzene can be easily removed by simple evaporation.
引用
收藏
页码：492 / 494
页数：3
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