New chiral phosphite ligands bearing sp2-nitrogen:: complexation properties and palladium(II)-catalysed enantioselective allylic alkylation

被引：32
|
作者：
Polosukhin, AI
Bondarev, OG
Lyubimov, SE
Korostylev, AV
Lyssenko, KA
Davankov, VA
Gavrilov, KN
机构：
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
[2] Ryazan State Pedag Univ, Dept Chem, Ryazan 390000, Russia
来源：
TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 15期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1016/S0957-4166(01)00382-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New homochiral P,N-bidentate phosphite-type ligands containing sp(2)-nitrogen were synthesised and their complexation with Rh(I) and Pd(II) atoms was investigated. The X-ray crystal structure of one of the chelate chlorocarbonyl rhodium complexes was obtained. E.e.s of up to 85% were attained in the Pd-catalysed allylic substitution reaction using the new P,N-ligands. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2197 / 2204
页数：8
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