Facile access to -acyloxyamides via epoxide rearrangement/three-component domino reaction catalyzed by indium(III) chloride

被引：12
|
作者：
Lingaswamy, Kadari [1 ]
Krishna, Palakodety Radha [1 ]
Prapurna, Y. Lakshmi [1 ]
机构：
[1] Indian Inst Chem Technol, CSIR, Organ & Biomol Chem Div, Discovery Lab, D-207, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2016年 / 46卷 / 15期
关键词：
Epoxides; highly regioselective; indium(III) chloride; tandem rearrangement; Passerini condensation; TosMIC; PASSERINI REACTION; MULTICOMPONENT REACTIONS; 3-COMPONENT REACTION; ISOCYANIDES; CHEMISTRY; ALDEHYDES; KETONES; ACID; ISONITRILES; DIVERSITY;
D O I：
10.1080/00397911.2016.1201511
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient Passerini reaction of epoxides involving highly regioselective rearrangement of epoxide to aldehyde/three-component Passerini reaction catalyzed by indium(III) chloride is described. In the present protocol, epoxides served as wonderful substrates to furnish a library of -acyloxyamides under mild reaction conditions in shorter reaction times and in good yields. [GRAPHICS]
引用
收藏
页码：1275 / 1282
页数：8
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