Ionically Self-Assembled Clustomesogen with Switchable Magnetic/Luminescence Properties Containing [Re6Se8(CN)6]n- (n=3, 4) Anionic Clusters

被引：68

作者：

Molard, Yann ^{[1
]}

Ledneva, Alexandra ^{[1
,3
]}

Amela-Cortes, Maria ^{[1
]}

Circu, Viorel ^{[4
]}

Naumov, Nikolai G. ^{[3
]}

Meriadec, Cristelle ^{[2
]}

Artzner, Franck ^{[2
]}

Cordier, Stephane ^{[1
]}

机构：

[1] Univ Rennes 1, Equipe Chim Solide & Mat, CNRS UR1 6226, UMR Sci Chim Rennes, F-35042 Rennes, France

[2] Univ Rennes 1, CNRS UR1 6251, UMR Inst Phys Rennes, F-35042 Rennes, France

[3] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[4] Univ Bucharest, Dept Inorgan Chem, Sect 2, Bucharest 020464, Romania

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 23期

关键词：

cluster compounds; hybrid materials; luminescence; liquid crystals; METAL ATOM CLUSTERS; ORGANIZED NANOSTRUCTURED COMPLEXES; HEXAPYRIDINE CLUSTERS; STATE; BR; METALLOMESOGENS; Q=S; MOLYBDENUM(II); LUMINESCENCE; SURFACTANTS;

D O I：

10.1021/cm201589d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Octahedral anionic rhenium clusters are obtained by high-temperature solid-state chemistry synthesis as single crystals or powders within which their charge is counter balanced by alkali cations. The ceramic-like behavior of the solid-state Re-6 based inorganic compound limits strongly their use in functional devices. We present herein a facile route to introduce these anionic dusters in a self-organized hybrid organic inorganic material. By replacing alkali countercations by mesogenic organic ones, polarized optical microscopy (POM), DSC, X-ray, magnetic, fluorescence, and cyclic voltammetry techniques confirm that a lyotropic and thermotropic liquid crystal material, able to switch reversibly from a bright red NW luminescent form to a magnetic green-colored one, is obtained.

引用

页码：5122 / 5130

页数：9

共 50 条

[1] Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re6Se8(PEt3)n(CN)6-n]n-4 (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re6Se8]2+ core
Gray, TG
Holm, RH
INORGANIC CHEMISTRY, 2002, 41 (16) : 4211 - 4216
[2] A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster:: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]
Kim, Sehye
Kim, Youngmee
Lee, Junghyun
Shin, Woonsup
Lee, Minyung
Kim, Sung-Jin
INORGANICA CHIMICA ACTA, 2007, 360 (06) : 1890 - 1894
[3] New Ligand Environment of the [Re6Se8]2+ Cluster Core: The Crystal Structure of the (n‐Bu4N)4[Re6Se8(CN)4Br2] · 4H2O Complex
S. B. Artemkina
N. G. Naumov
A. V. Virovets
V. E. Fedorov
Journal of Structural Chemistry, 2002, 43 : 689 - 693
[4] New ligand environment of the [Re6Se8]2+ cluster core:: The crystal structure of the (n-Bu4N)4[Re6Se8(CN)4Br2]•4H2O complex
Artemkina, SB
Naumov, NG
Virovets, AV
Fedorov, VE
JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (04) : 689 - 693
[5] From K6[Re6-xMoxS8(CN)5] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re4Mo2S8(CN)6]n- and [Re3Mo3S8(CN)6]n- Heterometallic Clusters
Lappi, Tatiana I.
Gayfulin, Yakov M.
Renaud, Adele
Prestipino, Carmelo
Lemoine, Pierric
Yanshole, Vadim V.
Muravieva, Viktoria K.
Cordier, Stephane
Naumov, Nikolai G.
MOLECULES, 2023, 28 (15):
[6] 23-Electron Re6 metal clusters: syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6]·8H2O, and (Et4N)2(H)[Re6Te8(CN)6]·2H2O
N. G. Naumov
E. V. Ostanina
A. V. Virovets
M. Schmidtman
A. Müller
V. E. Fedorov
Russian Chemical Bulletin, 2002, 51 : 866 - 871
[7] Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance
Bennett, MV
Beauvais, LG
Shores, MP
Long, JR
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) : 8022 - 8032
[8] 23-Electron Re6 metal clusters:: Syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6] • 8H2O, and (Et4N)2(H)[Re6Te8(CN)6] • 2H2O
Naumov, NG
Ostanina, EV
Virovets, AV
Schmidtman, M
Müller, A
Fedorov, VE
RUSSIAN CHEMICAL BULLETIN, 2002, 51 (05) : 866 - 871
[9] Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(μ-OH)4(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6]•2H2O
Xu, Li
Kim, Youngmee
Kim, Sung-Jin
Kim, Hee Jin
Kim, Cheal
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (05) : 586 - 589
[10] Apical Cyanide Ligand Substitution in Heterometallic Clusters [Re3Mo3Q8(CN)6]n- (Q = S, Se)
Muravieva, Viktoria K.
Gayfulin, Yakov M.
Lappi, Tatiana I.
Dorcet, Vincent
Sukhikh, Taisiya S.
Lemoine, Pierric
Ryzhikov, Maxim R.
Mironov, Yuri V.
Cordier, Stephane
Naumov, Nikolay G.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (22) : 2685 - 2690

← 1 2 3 4 5 →