Electron-Induced Hydration of an Alkene: Alternative Reaction Pathways

被引：18
|
作者：
Warneke, Jonas [1 ]
Wang, Ziyan [1 ]
Swiderek, Petra [1 ]
Bredehoeft, Jan Hendrik [1 ]
机构：
[1] Univ Bremen, Inst Angew & Phys Chem, D-28359 Bremen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 14期
关键词：
alkenes; electron-induced reactions; radical ions; reaction mechanisms; water; LOW-ENERGY ELECTRONS; INDUCED HYDROAMINATION; DISSOCIATION; MOLECULES; HYDROCARBONS; ATTACHMENT; ETHYLENE; FILMS; DNA;
D O I：
10.1002/anie.201412147
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electron-induced reactions in condensed mixtures of ethylene and water lead to the synthesis of ethanol, as shown by post-irradiation thermal desorption spectrometry (TDS). Interestingly, this synthesis is not only induced by soft electron impact ionization similar to a previously observed electron-induced hydroamination but also, at low electron energy, by electron attachment to ethylene and a subsequent acid/base reaction with water.
引用
收藏
页码：4397 / 4400
页数：4
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