Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light

被引：650
|
作者：
Neumann, Matthias [1 ]
Fueldner, Stefan [1 ]
Koenig, Burkhard [1 ]
Zeitler, Kirsten [1 ]
机构：
[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 04期
关键词：
asymmetric alkylation; cooperative catalysis; organocatalysis; photocatalysis; xanthene dyes; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; PHOTOINDUCED ELECTRON-TRANSFER; SENSITIZED SOLAR-CELLS; PHOTOREDOX CATALYSIS; PHENACYL HALIDES; DOMINO REACTIONS; XANTHENE DYES; ORGANIC-DYES; ALDEHYDES; ALKYLATION;
D O I：
10.1002/anie.201002992
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dawn of old stars: Classic xanthene dyes like eosin Y (gr. I=goddess of dawn) and green-light irradiation can replace precious metal complexes for the organocatalytic asymmetric α-alkylation of aldehydes, thus rendering the process purely organic. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：951 / 954
页数：4
相关论文
共 50 条
  • [1] Catalytic, metal-free sulfonylcyanation of alkenes via visible light organophotoredox catalysis
    Sun, Jianfeng
    Li, Peng
    Guo, Lei
    Yu, Fang
    He, Yu-Peng
    Chu, Lingling
    CHEMICAL COMMUNICATIONS, 2018, 54 (25) : 3162 - 3165
  • [2] Metal-Free Perfluoroarylation by Visible Light Photoredox Catalysis
    Meyer, Andreas U.
    Slanina, Tomas
    Yao, Chang-Jiang
    Koenig, Burkhard
    ACS CATALYSIS, 2016, 6 (01): : 369 - 375
  • [3] Metal-Free Synthesis of α-Iminonitriles via Visible Light Photoredox Catalysis
    Liu, Wen-Hao
    Liu, Run-Jiao
    Liu, Xing-Yuan
    Zhao, Han-Qing
    Xia, Zi-Hao
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 12 (11)
  • [4] Metal-Free Thiocyanation of Imidazoheterocycles through Visible Light Photoredox Catalysis
    Mitra, Shubhanjan
    Ghosh, Monoranjan
    Mishra, Subhajit
    Hajra, Alakananda
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (16): : 8275 - 8281
  • [5] Metal-Free Desulfonylation Reaction Through Visible-Light Photoredox Catalysis
    Yang, Deng-Tao
    Meng, Qing-Yuan
    Zhong, Jian-Ji
    Xiang, Ming
    Liu, Qiang
    Wu, Li-Zhu
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (33) : 7528 - 7532
  • [6] Continuous Flow α-Trifluoromethylation of Ketones by Metal-Free Visible Light Photoredox Catalysis
    Cantillo, David
    de Frutos, Oscar
    Rincon, Juan A.
    Mateos, Carlos
    Kappe, C. Oliver
    ORGANIC LETTERS, 2014, 16 (03) : 896 - 899
  • [7] Metal-free visible-light-mediated organophotoredox catalysis: synthesis of 3-functionalized indole via C–C, C–N bond formation
    Neetu Yadav
    Mohd Danish Ansari
    Vijay B. Yadav
    Ankit Verma
    Saurabh K. Tiwari
    Saif Ansari
    I. R. Siddiqui
    Molecular Diversity, 2021, 25 : 1103 - 1109
  • [8] Metal-free radical trifluoromethylation of β-nitroalkenes through visible-light photoredox catalysis
    Midya, Siba P.
    Rana, Jagannath
    Abraham, Thomas
    Aswin, Bhaskaran
    Balaraman, Ekambaram
    CHEMICAL COMMUNICATIONS, 2017, 53 (50) : 6760 - 6763
  • [9] Metal-free C-H sulfonamidation of pyrroles by visible light photoredox catalysis
    Meyer, Andreas Uwe
    Berger, Anna Lucia
    Koenig, Burkhard
    CHEMICAL COMMUNICATIONS, 2016, 52 (72) : 10918 - 10921
  • [10] A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones
    Rostoll-Berenguer, Jaume
    Blay, Gonzalo
    Carmen Munoz, M.
    Pedro, Jose R.
    Vila, Carlos
    ORGANIC LETTERS, 2019, 21 (15) : 6011 - 6015
12345