1,2-bis(5-methyl-4-methylthio-1,3-dithiolium-2-ylidene)-1,2-diphenylethane bis(triiodide) and 1,2-bis(4-methoxyphenyl)-1,2-bis(5-methyl-4-methylthio-1,3-dithiolium-2-ylidene)ethane diperchlorate

被引:9
|
作者
Rimbaud, C
Le Magueres, P
Ouahab, L
Lorcy, D
Robert, A
机构
[1] Univ Rennes 1, Grp Mat Mol, Chim Solide & Inorgan Mol Lab, CNRS,UMR 6511, F-35042 Rennes, France
[2] Univ Rennes 1, Lab Synth & Electrosynthese Organ, UMR 6510, F-35042 Rennes, France
关键词
D O I
10.1107/S010827019701768X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The non-planar organic donor 1,2-diaryl-1,2-bis(5-methyl-4-methylthio-1,3-dithiol-2-ylidene)ethane forms dication charge-transfer salts with iodine, C24H22S62+.2I(3)(-), and with perchlorate, C26H26O2S62+.2ClO(4)(-). In the former salt, mixed stacks of triiodide and dications are observed, while separated organic and inorganic columns are found in the perchlorate salt.
引用
收藏
页码:679 / 681
页数:3
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