Amino-functionalized carbon nanofibres as an efficient metal free catalyst for the synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and 2-aminobenzonitriles

被引：22

作者：

Kumar, Subodh ^{[1
]}

Verma, Sanny ^{[1
]}

Shawat, Efrat ^{[2
]}

Nessim, Gilbert Daniel ^{[2
]}

Jain, Suman L. ^{[1
]}

机构：

[1] CSIR, Indian Inst Petr, Div Chem Sci, Dehra Dun 248005, Uttar Pradesh, India

[2] Bar Ilan Univ, Bar Ilan Inst Nanotechnol & Adv Mat BINA, Dept Chem, IL-52900 Ramat Gan, Israel

来源：

RSC ADVANCES | 2015年 / 5卷 / 31期

关键词：

DIOXIDE; DERIVATIVES; NANOTUBES; 1H-QUINAZOLINE-2,4-DIONES; CONVERSION; FIXATION; WATER;

D O I：

10.1039/c5ra01900a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon nanofibres (CNFs) functionalized with 4-amino-2,6-dimethylpyridine were found to be an efficient metal free catalyst for the synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and 2-aminobenzonitriles using water as a reaction medium. The presence of water they exhibited a remarkable enhancement in reaction rates and provided high to excellent yield of the products. After completion of the reaction, the catalyst was easily separated by centrifugation and was successfully reused for several runs without showing any significant decrease in catalytic activity.

引用

页码：24670 / 24674

页数：5

共 50 条

[1] Efficient synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and 2-aminobenzonitriles in water without any catalyst
Ma, Jun
Han, Buxing
Song, Jinliang
Hu, Jiayin
Lu, Wenjing
Yang, Dezhong
Zhang, Zhaofu
Jiang, Tao
Hou, Minqiang
GREEN CHEMISTRY, 2013, 15 (06) : 1485 - 1489
[2] Cesium carbonate catalyzed efficient synthesis of quinazoline-2,4(1H,3H)-diones using carbon dioxide and 2-aminobenzonitriles
Patil, Yogesh P.
Tambade, Pawan J.
Jagtap, Sachin R.
Bhanage, Bhalchandra M.
GREEN CHEMISTRY LETTERS AND REVIEWS, 2008, 1 (02) : 127 - 132
[3] Synthesis of quinazoline-2,4(1H,3H)-diones from carbon dioxide and 2-aminobenzonitriles using [Bmim]OH as a homogeneous recyclable catalyst
Patil, Yogesh P.
Tambade, Pawan J.
Deshmukh, Krishna M.
Bhanage, Bhalchandra M.
CATALYSIS TODAY, 2009, 148 (3-4) : 355 - 360
[4] Synthesis of Quinazoline-2,4(1H,3H)-Diones from Carbon dioxide and 2-Aminobenzonitriles Using MgO/ZrO2 as a Solid Base Catalyst
Yogesh P. Patil
Pawan J. Tambade
Kalpesh D. Parghi
Radha V. Jayaram
Bhalchandra M. Bhanage
Catalysis Letters, 2009, 133 : 201 - 208
[5] Amine functionalized MCM-41: an efficient heterogeneous recyclable catalyst for the synthesis of quinazoline-2,4(1H,3H)-diones from carbon dioxide and 2-aminobenzonitriles in water
Nale, Deepak B.
Rana, Surjyakanta
Parida, Kulamani
Bhanage, Bhalchandra M.
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1608 - 1614
[6] Synthesis of Quinazoline-2,4(1H,3H)-Diones from Carbon dioxide and 2-Aminobenzonitriles Using MgO/ZrO2 as a Solid Base Catalyst
Patil, Yogesh P.
Tambade, Pawan J.
Parghi, Kalpesh D.
Jayaram, Radha V.
Bhanage, Bhalchandra M.
CATALYSIS LETTERS, 2009, 133 (1-2) : 201 - 208
[7] Efficient [WO4]2--Catalyzed Chemical Fixation of Carbon Dioxide with 2-Aminobenzonitriles to Quinazoline-2,4(1H,3H)-diones
Kimura, Toshihiro
Sunaba, Hanako
Kamata, Keigo
Mizuno, Noritaka
INORGANIC CHEMISTRY, 2012, 51 (23) : 13001 - 13008
[8] Chemical fixation of CO2 to 2-aminobenzonitriles: A straightforward route to quinazoline-2,4(1H,3H)-diones with green and sustainable chemistry perspectives
Vessally, Esmail
Soleimani-Amiri, Somayeh
Hosseinian, Akram
Edjlali, Ladan
Babazadeh, Mirzaagha
JOURNAL OF CO2 UTILIZATION, 2017, 21 : 342 - 352
[9] Spidery catalyst for the synthesis of quinazoline-2,4(1H,3H)-diones
Sadeghzadeh, Seyed Mohsen
CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (05) : 1435 - 1441
[10] Highly Efficient Synthesis of Quinazoline-2,4(1H,3H)-diones from CO2 by Hydroxyl Functionalized Aprotic Ionic Liquids
Shi, Guiling
Chen, Kaihong
Wang, Yongtao
Li, Haoran
Wang, Congmin
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (05): : 5760 - 5765

← 1 2 3 4 5 →