One-Pot Synthesis of Benzo[d][1,3]selenazole Derivatives by Using Carbon-Supported Copper Catalyst

被引：3

作者：

Zhou, Meiyun ^{[1
]}

Wu, Zhaojun ^{[1
]}

Li, Yiquan ^{[1
]}

Zheng, Wenjie ^{[1
]}

Ji, Shengbin ^{[1
]}

Zhou, Hua ^{[2
]}

机构：

[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China

[2] Jinan Univ, Dept Food Sci & Engn, Guangzhou 510632, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 06期

基金：

中国国家自然科学基金;

关键词：

one-pot synthesis; benzo[d][1,3]selenazole; carbon-supported copper; SINGLET OXYGEN GENERATION; CROSS-COUPLING REACTIONS; SELENIUM; CYCLIZATION;

D O I：

10.6023/cjoc201412021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, efficient, inexpensive one-pot method for the benzo[d][1,3]selenazole derivatives synthesized from 2-bromoaniline was developed by using cheap carbon-supported copper as catalyst at room temperature. The reaction provides an efficient protocol to a series of benzo[d][1,3]selenazole derivatives in good to high yields, and benefits of readily available catalyst and synthesis of high efficiency.

引用

页码：1270 / 1275

页数：6

共 16 条

[1] Bayoumy K., 2004, MUTAT RES-FUND MOL M, V551, P81
[2] Copper in cross-coupling reactions - The post-Ullmann chemistry
Beletskaya, IP
Cheprakov, AV
[J]. COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) : 2337 - 2364
[3] Interactions among supported copper-based catalyst components and their effects on performance: A review
Dong Lin
Yao Xiaojiang
Chen Yi
[J]. CHINESE JOURNAL OF CATALYSIS, 2013, 34 (05) : 851 - 864
[4] Catalytic C-S, C-Se, and C-P Cross-Coupling Reactions Mediated by a CuI/CuIII Redox Cycle
Font, Marc
Parella, Teodor
Costas, Miquel
Ribas, Xavi
[J]. ORGANOMETALLICS, 2012, 31 (22) : 7976 - 7982
[5] Copper(I)-catalyzed highly efficient synthesis of benzoselenazoles and benzotellurazoles
Fujiwara, Shin-ichi
Asanuma, Yoshiaki
Shin-ike, Tsutomu
Kambe, Nobuaki
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (21): : 8087 - 8090
[6] Govindasamy M., 2013, Curr. Chem. Biol., V7, P47, DOI 10.2174/2212796811307010005
[7] One-pot copper-catalyzed tandem addition-cyclization of 2-iodoanilines with isoselenocyanates for the practical preparation of 2-aminobenzoselenazoles
Kaname, Mamoru
Minoura, Mao
Sashida, Haruki
[J]. TETRAHEDRON LETTERS, 2011, 52 (04) : 505 - 508
[8] Modern synthetic methods for copper-mediated C(aryl)-O, C(aryl)-N, and C(aryl)-S bond formation
Ley, SV
Thomas, AW
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (44) : 5400 - 5449
[9] Selenium-containing Coordinating Assemblies with Selective Anti-cancer Activity: the Control of Reactive Oxygen Species
Li Tianyu
Yi Yu
Xu Huaping
[J]. ACTA CHIMICA SINICA, 2014, 72 (10) : 1079 - 1084
[10] Synthesis of dimethyl carbonate over starch-based carbon-supported Cu nanoparticles catalysts
Ren, Jun
Guo, Changjiang
Yang, Leilei
Li, Zhong
[J]. CHINESE JOURNAL OF CATALYSIS, 2013, 34 (09) : 1734 - 1744

← 1 2 →