Influence of the Reactive Processing of Recycled Poly(ethylene terephthalate)/Poly(ethylene-co-glycidyl methacrylate) Blends

被引:15
|
作者
Kunimune, Noriaki [2 ]
Yamada, Kazushi [1 ]
Leong, Yew Wei [3 ]
Thumsorn, Supaphorn [3 ]
Hamada, Hiroyuki [3 ]
机构
[1] Kyoto Inst Technol, Future Appl Convent Technol Ctr, Sakyo Ku, Kyoto 6068585, Japan
[2] Kunimune Co Ltd, Higashiosaka, Osaka 5770053, Japan
[3] Kyoto Inst Technol, Div Adv Fibrosci, Sakyo Ku, Kyoto 6068585, Japan
关键词
blending; impact resistance; injection molding; polyesters; recycling; DENSITY POLYETHYLENE ALLOYS; POLY(BUTYLENE TEREPHTHALATE); POLY(ETHYLENE-TEREPHTHALATE); COPOLYMER; COMPATIBILIZATION; IONOMER;
D O I
10.1002/app.32836
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of the amount of reactive additive and screw speed during extrusion on the morphological characteristics and mechanical performance of recycled poly(ethylene terephthalate)(RPET) was investigated. With an increase in the ethylene-glycidyl methacrylate copolymer (E-GMA) additive content, a gradual increase in the Izod impact strength of the RPET/E-GMA blends was initially recorded. Subsequent increases in the E-GMA content to above 13.5 wt % led to a drastic enhancement in the toughness of the blends. Meanwhile, the density of the blends decreased with increasing amount of the additive E-GMA. The toughness and density of the blends were found to be dependent on the screw rotation speed during the extrusion. In addition, ductile and microporous structures were observed on the Izod impact fracture surfaces. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 50-55, 2011
引用
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页码:50 / 55
页数:6
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