Iron-catalysed green synthesis of carboxylic esters by the intermolecular addition of carboxylic acids to alkenes

被引：31

作者：

Choi, Jun-Chul ^{[1
]}

Kohno, Kazufumi ^{[1
]}

Masuda, Daisuke ^{[1
]}

Yasuda, Hiroyuki ^{[1
]}

Sakakura, Toshiyasu ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 06期

关键词：

D O I：

10.1039/b713951a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron triflate, in situ-formed from FeCl3 and triflic acid, or FeCl3 and silver triflate efficiently catalyse the intermolecular addition of carboxylic acids to various alkenes to yield carboxylic esters; the reaction is applicable to the synthesis of unstable esters, such as acrylates.

引用

页码：777 / 779

页数：3

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