Absence of Dopant Segregation to the Surface of Scandia and Yttria Co-Stabilized Zirconia

被引：6

作者：

Hansenz, Karin Vels ^{[1
]}

Mogensen, Mogens ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2012年 / 15卷 / 05期

关键词：

CONDUCTIVITY; FLUORITE; IMPURITY; SYSTEM;

D O I：

10.1149/2.003206esl

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The surface composition of sintered scandia and yttria co-stabilized zirconia was analyzed with x-ray photoelectron spectroscopy. The samples were sintered at 1300 degrees C or 1500 degrees C in flowing dry or moisturized air. It was found that Sc2O3 does not segregate to the surface, unlike the Y2O3 in yttria stabilized zirconia. The probable reason for this is that due to its size the Sc3+ ion fits better in the zirconia lattice than Y3+ does. The difference in surface composition may be the explanation for the observed increased tolerance toward sulfur of Ni-ScYSZ compared to Ni-YSZ cermets. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.003206esl] All rights reserved.

引用

页码：B70 / B71

页数：2

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