A BINOL Based Fluorescence Sensor for Distinction of D-Glucose

被引：9
|
作者：
Xu, Bangyu [1 ]
Hou, Jiting [1 ]
Li, Kun [1 ]
Lu, Zhengwei [1 ]
Yu, Xiaoqi [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Sichuan, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 01期
基金：
美国国家科学基金会;
关键词：
1,1 '-binaphthol; boronic acid; D-glucose; distinction; BORONIC ACID; RECOGNITION; CHEMOSENSORS; RECEPTOR; CHEMODOSIMETER; SACCHARIDES; COMPLEXES; ANION;
D O I：
10.1002/cjoc.201400120
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A saccharide fluorescent receptor based on 1,1 '-binaphthol was developed. The boronic acids groups are directly attached to the 3,3 '-positions of BINOL which acted as probes to saccharides. The methyl protected receptor R1 showed better response to D-fructose compared to other saccharides in the fluorescence quenching experiment. To improve the selectivity of D-glucose, the triethylene glycol protected receptor R2 was developed. Receptor R2 has a better water-solubility than R1 that can be applied in completely aqueous environment. With receptor R2, D-glucose has a different response to other saccharides that can be useful for the distinction of D-glucose.
引用
收藏
页码：101 / 106
页数：6
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