Synergistic effect, kinetics, and pollutant emission characteristics of co-combustion of polymer-containing oily sludge and cornstalk using TGA and fixed-bed reactor

被引:19
|
作者
Cao, Yuhao [1 ]
Liu, Yanxing [2 ]
Li, Zhengyuan [3 ]
Zong, Peiying [1 ]
Hou, Jiachen [1 ]
Zhang, Qiyan [1 ]
Gou, Xiang [1 ]
机构
[1] Hebei Univ Technol, Sch Energy & Environm Engn, Tianjin 300401, Peoples R China
[2] UCL, Dept Earth Sci, Gower St, London WC1E 6BT, England
[3] UCL, Dept Chem, Gower St, London WC1E 6BT, England
关键词
Synergistic effect; Co-combustion; Cornstalk; Polymer-containing oily sludge; NO; SO2; HYDROTHERMAL CARBONIZATION; THERMOGRAVIMETRIC ANALYSIS; COMBUSTION; PYROLYSIS; COAL; MICROALGAE; BEHAVIOR; BIOMASS; WATER;
D O I
10.1016/j.renene.2021.12.039
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The synergistic effect of co-combustion of polymer-containing oily sludge (POS) and cornstalk (CS) was investigated by thermogravimetric analyzer (TGA) and fixed-bed reactor. The TGA results show that the co-combustion process of POS-CS can be divided into three stages: the evaporation of the oil-water, combustion of volatiles and light oil, and the coupled combustion of heavy oil, fixed carbon, and organic matter. With CS ratios from 30% to 70%, the ignition index and comprehensive combustion index of POS increase by 1.18-2.33 times and 1.53 to 3.95 times, respectively. The POS-CS blends have an inhibitory effect in the temperature range of 180-260 & DEG;C and 420-495 & DEG;C, however, a synergistic effect is exhibited throughout the entire temperature range. The activation energies of the blends are 33%, 45%, 41%, 35% and 53% lower than that of POS, at the CS ratios of 30%, 40%, 50%, 60% and 70%, respectively. The fixed-bed experiments indicate that the emissions of NO and SO2 decrease with the increase of CS. Specifically, the NO and SO2 emissions of the blend with CS ratio of 70% are 2.86 mg g(-1) and 3.49 mg g(-1), which decrease by 31.6% and 37.8%, compared with POS, respectively. In addition, the pollutant level (NO and SO2) of POS-CS blends is also lower than some typical solid fuels. (c) 2021 Published by Elsevier Ltd.
引用
收藏
页码:748 / 758
页数:11
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