Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis

被引：657
|
作者：
Aleman, Jose [1 ]
Parra, Alejandro [3 ,4 ]
Jiang, Hao [2 ]
Jorgensen, Karl Anker [2 ]
机构：
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ Modulo 1, E-28049 Madrid, Spain
[2] Aarhus Univ, Dept Chem, Ctr Catalysis, DK-8000 Aarhus C, Denmark
[3] Harvard Univ, Lab Prof Andrew Myers, Cambridge, MA 02138 USA
[4] Univ Autonoma Madrid, E-28049 Madrid, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 25期
关键词：
asymmetric synthesis; bifunctional catalysts; molecular recognition; organocatalysis; ENANTIOSELECTIVE MICHAEL ADDITION; HYDROGEN-BONDING INTERACTIONS; CONJUGATE ADDITION; HENRY REACTION; ASYMMETRIC CATALYSIS; 1,3-DICARBONYL COMPOUNDS; CHIRAL SQUARAMIDES; DIPHENYL PHOSPHITE; THIOUREA CATALYST; NITROOLEFINS;
D O I：
10.1002/chem.201003694
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed.
引用
收藏
页码：6890 / 6899
页数：10
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