Oxidation of plutonium dioxide: an X-ray absorption spectroscopy study

被引:43
|
作者
Martin, P
Grandjean, S
Ripert, M
Freyss, M
Blanc, P
Petit, T
机构
[1] CEA Cadarache, DEN, DEC, SESC,LLCC, F-13108 St Paul Les Durance, France
[2] CEA Marcoule, DEN, DRCP, SCPS, F-30207 Bagnols Sure Ceze, France
关键词
D O I
10.1016/S0022-3115(03)00180-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
X-ray absorption spectroscopy experiments were conducted in order to characterise plutonium dioxide oxidation. It is shown that the sample preparation adopted does not enable elaboration of hyperstoichiometric plutonium dioxide. These results could mean that plutonium dioxide oxidation only occurs under very specific conditions. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:138 / 141
页数:4
相关论文
共 50 条
  • [1] Oxidation state determination of plutonium aquo ions using x-ray absorption spectroscopy
    Conradson, SD
    Al Mahamid, I
    Clark, DL
    Hess, NJ
    Hudson, EA
    Neu, MP
    Palmer, PD
    Runde, WH
    Tait, CD
    POLYHEDRON, 1998, 17 (04) : 599 - 602
  • [2] A study of xenon aggregates in uranium dioxide using X-ray absorption spectroscopy
    Garcia, P.
    Martin, P.
    Carlot, G.
    Castelier, E.
    Ripert, M.
    Sabathier, C.
    Valot, C.
    D'Acapito, F.
    Hazemann, J. -L.
    Proux, O.
    Nassif, V.
    JOURNAL OF NUCLEAR MATERIALS, 2006, 352 (1-3) : 136 - 143
  • [3] A X-RAY STUDY OF OXIDATION OF URANIUM DIOXIDE
    BESSONOV, AF
    STREKALO.VN
    USTYANTS.VM
    SOVIET PHYSICS CRYSTALLOGRAPHY, USSR, 1966, 10 (04): : 480 - &
  • [4] Energy calibrations in the x-ray absorption spectroscopy of uranium dioxide
    Yu, Sung Woo
    Tobin, J. G.
    Olalde-Velasco, Paul
    Yang, Wan Li
    Siekhaus, Wigbert J.
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2012, 30 (01):
  • [5] An X-ray absorption spectroscopy study of Mo oxidation in Pb at elevated temperatures
    Liu, Shanshan
    Olive, Daniel
    Terry, Jeff
    Segre, Carlo U.
    JOURNAL OF NUCLEAR MATERIALS, 2009, 392 (02) : 259 - 263
  • [6] X-RAY PHOTOEMISSION SPECTROSCOPY STUDY OF NEPTUNIUM AND PLUTONIUM DIOXIDES
    LAM, DJ
    VEAL, BW
    DIAMOND, H
    CARNALL, WT
    HOEKSTRA, HR
    JOM-JOURNAL OF METALS, 1975, 27 (12): : A17 - A17
  • [7] X-ray absorption spectroscopy study of nanotubes
    Bellucci, S
    Botti, S
    Marcelli, A
    Ibrahim, K
    Wu, ZY
    X-RAY AND INNER-SHELL PROCESSES, 2003, 652 : 355 - 361
  • [8] X-ray absorption fine structure spectroscopy of plutonium complexes with Bacillus sphaericus
    Panak, PJ
    Booth, CH
    Caulder, DL
    Bucher, JJ
    Shuh, DK
    Nitsche, H
    RADIOCHIMICA ACTA, 2002, 90 (06) : 315 - 321
  • [9] VANADIUM OXIDATION STATE DETERMINATION BY X-RAY ABSORPTION SPECTROSCOPY
    Duchesne, Marc A.
    Nakano, Jinichiro
    Hu, Yongfeng
    MacLennan, Aimee
    Hughes, Robin W.
    Bennett, James
    Nakano, Anna
    ADVANCES IN MOLTEN SLAGS, FLUXES, AND SALTS, 2016, : 1405 - 1412
  • [10] Understanding Photoelectrochemical Water Oxidation with X-ray Absorption Spectroscopy
    Deng, Jiujun
    Zhang, Qingzhe
    Lv, Xiaoxin
    Zhang, Duo
    Xu, Hui
    Ma, Dongling
    Zhong, Jun
    ACS ENERGY LETTERS, 2020, 5 (03) : 975 - 993