Experimental and actual values of self-diffusion coefficients of liquids in porous media

被引:0
|
作者
Tyurin, V. A. [1 ]
Maklakov, A. I. [1 ]
机构
[1] Kazan VI Lenin State Univ, Kazan 420008, Tatarstan, Russia
关键词
Diffusion Time; Colloid Journal; Glass Sphere; Spin Dephasing; Short Correlation Time;
D O I
10.1134/S1061933X07060166
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-diffusion coefficients D* of liquids in porous media, as measured by the pulsed-field gradient NMR method, have been investigated as functions of the interval t(1) between the first and the second radio-frequency pulses (the time of spin dephasing) in the "stimulated echo" pulsed procedure. Experimental D*(t(1)) dependences have been shown to be adequately described by the relations of the Fatkullin theory for moderate and short correlation times of spin motion in an internal random Gaussian magnetic field. Actual self-diffusion coefficients and some parameters of the porous media have been estimated.
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页码:786 / 791
页数:6
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