Bis{μ-[6-(hydroxymethyl)-2-pyridyl]methanolato-κ3N,O:O}bis{[2,6-bis(hydroxymethyl)pyridine-κ3O,N,O′]-copper(II)} diacetate

被引：7
|
作者：
Gupta, AK [1 ]
Kim, J [1 ]
机构：
[1] Kongju Natl Univ, Dept Chem, Kong Ju 314701, Chungnam, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词：
D O I：
10.1107/S0108270103009326
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title dinuclear Cu-II complex, [Cu-2(G(7)H(8)NO(2))(2)(G(7)H(9)NO(2))(2)](CH3COO)(2), has been synthesized by the reaction of Cu(CH3COO)(2).H2O with pdmH(2) (pdmH(2) is pyridine-2,6-diyldimethanol) in the presence of tetrabutylammonium hydroxide. The title complex contains a centrosymmetric Cu2O2 core and each Cu-II atom has distorted octahedral geometry. Molecular [Cu-2(pdmH)(2)(pdmH(2))](2+) cations are connected by hydrogen bonds involving the CH3COO- anions, forming one-dimensional chains along the a axis.
引用
收藏
页码：M262 / M264
页数：3
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