Gold-Nanoparticle-Loaded Carbonate-Modified Titanium(IV) Oxide Surface: Visible-Light-Driven Formation of Hydrogen Peroxide from Oxygen

被引：128
|
作者：
Teranishi, Miwako [1 ]
Hoshino, Riyoko [2 ]
Naya, Shin-ichi [1 ]
Tada, Hiroaki [2 ]
机构：
[1] Kindai Univ, Environm Res Lab, 3-4-1 Kowakae, Osaka 5778502, Japan
[2] Kindai Univ, Dept Appl Chem, Sch Sci & Engn, 3-4-1 Kowakae, Osaka 5778502, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 41期
关键词：
hydrogen peroxide; oxygen reduction reaction; plasmonics; photocatalysis; solar chemical transformations; MOLECULAR-OXYGEN; TIO2; SURFACES; PHOTOCATALYSTS; OXIDATION; DIOXIDE; RUTILE; WATER; DEPENDENCE; PARTICLES;
D O I：
10.1002/anie.201606734
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold nanoparticle-loaded rutile TiO2 with a bimodal size distribution around 10.6nm and 2.3nm (BM-Au/TiO2) was prepared by the deposition precipitation and chemical reduction (DP-CR) technique. Visible-light irradiation (>430nm) of the BM-Au/TiO2 plasmonic photocatalyst yields 35m H2O2 in aerated pure water at irradiation time (t(p))=1h, and the H2O2 concentration increases to 640 +/- 60m by the addition of 4% HCOOH as a sacrificing electron donor. Further, a carbonate-modified surface BM-Au/TiO2 (BM-Au/TiO2-CO32-) generates a millimolar level of H2O2 at t(p)=1h with a quantum efficiency (phi) of 5.4% at =530nm under the same conditions. The recycle experiments confirmed the stable performance of BM-Au/TiO2.
引用
收藏
页码：12773 / 12777
页数：5
相关论文
共 10 条
  • [1] Visible-Light Activity Enhancement of Gold-Nanoparticle-Loaded Titanium(IV) Dioxide by Preferential Excitation of Localized Surface Plasmon Resonance
    Naya, Shin-ichi
    Inoue, Aimi
    Tada, Hiroaki
    CHEMPHYSCHEM, 2011, 12 (15) : 2719 - 2723
  • [2] Temperature- and pH-Dependence of Hydrogen Peroxide Formation from Molecular Oxygen by Gold Nanoparticle-Loaded Titanium(IV) Oxide Photocatalyst
    Teranishi, Miwako
    Naya, Shin-ichi
    Tada, Hiroaki
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (02): : 1083 - 1088
  • [3] In Situ Liquid Phase Synthesis of Hydrogen Peroxide from Molecular Oxygen Using Gold Nanoparticle-Loaded Titanium(IV) Dioxide Photocatalyst
    Teranishi, Miwako
    Naya, Shin-ichi
    Tada, Hiroaki
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (23) : 7850 - +
  • [4] Visible-Light-Induced Electron Transport from Small to Large Nanoparticles in Bimodal Gold Nanoparticle-Loaded Titanium(IV) Oxide
    Naya, Shin-ichi
    Niwa, Tadahiro
    Kume, Takahiro
    Tada, Hiroaki
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (28) : 7305 - 7309
  • [5] Visible-light-driven hydrogen peroxide production from water and dioxygen by perylenetetracarboxylic diimide modified titanium-based metal-organic frameworks
    Chen, Xiaolang
    Kondo, Yoshifumi
    Li, Shuangjun
    Kuwahara, Yasutaka
    Mori, Kohsuke
    Zhang, Dieqing
    Louis, Catherine
    Yamashita, Hiromi
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (46) : 26371 - 26380
  • [6] Visible light-induced hydrogen evolution from aqueous suspensions of titanium(IV) oxide modified with binaphthol
    Ikeda, S
    Abe, C
    Torimoto, T
    Ohtani, B
    ELECTROCHEMISTRY, 2002, 70 (06) : 442 - 445
  • [7] Introduction of a secondary ligand into titanium-based metal-organic frameworks for visible-light-driven photocatalytic hydrogen peroxide production from dioxygen reduction
    Chen, Xiaolang
    Kuwahara, Yasutaka
    Mori, Kohsuke
    Louis, Catherine
    Yamashita, Hiromi
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (05) : 2815 - 2821
  • [8] Photochemical hydrogen evolution from aqueous triethanolamine solutions sensitized by binaphthol-modified titanium(IV) oxide under visible-light irradiation
    Ikeda, S
    Abe, C
    Torimoto, T
    Ohtani, B
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 160 (1-2) : 61 - 67
  • [9] Visible-Light-Driven Room Temperature NO2 Gas Sensor Based on Localized Surface Plasmon Resonance: The Case of Gold Nanoparticle Decorated Zinc Oxide Nanorods (ZnO NRs)
    Qomaruddin, Olga
    Casals, Olga
    Wasisto, Hutomo Suryo
    Waag, Andreas
    Prades, Joan Daniel
    Fabrega, Cristian
    CHEMOSENSORS, 2022, 10 (01)
  • [10] Hydrogen Peroxide Production from Oxygen and Water by Two-electrode Electrolytic Cell Using a Gold Nanoparticle-loaded Fluorine-doped Tin Oxide Cathode
    Kunimoto, Takeshi
    Naya, Shin-ichi
    Tada, Hiroaki
    CHEMISTRY LETTERS, 2021, 50 (08) : 1589 - 1591
1