PS-BQ: an efficient polymer-supported cocatalyst for the Wacker reaction in supercritical carbon dioxide

被引：38
|
作者：
Wang, ZY
Jiang, HF [1 ]
Qi, CR
Wang, YG
Dong, YS
Liu, HL
机构：
[1] S China Univ Technol, Ctr Green Chem, Guangzhou 510640, Peoples R China
[2] S China Normal Univ, Sch Chem & Environm, Dept Chem, Guangzhou 510631, Peoples R China
来源：
GREEN CHEMISTRY | 2005年 / 7卷 / 08期
关键词：
D O I：
10.1039/b505515f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Using polystyrene-supported benzoquinone (PS-BQ) as cocatalyst with palladium chloride, the acetalization of terminal olefins with electron-withdrawing groups, i.e., acrylate esters, acrylonitrile, methyl vinyl ketone and acrolein, was carried out smoothly in supercritical carbon dioxide under oxygen atmosphere.
引用
收藏
页码：582 / 585
页数：4
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