Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)

被引：14

作者：

Lundrigan, Travis ^{[1
]}

Jackson, Carla L. M. ^{[1
]}

Uddin, Md Imam ^{[1
]}

Tucker, Lloyd A. ^{[1
]}

Ali, Adeeb Al-Sheikh ^{[1
,2
]}

Linden, Anthony ^{[3
]}

Cameron, T. Stanley ^{[1
]}

Thompson, Alison ^{[1
]}

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada

[2] Taibah Univ, Dept Chem, Al Munawarrah, Saudi Arabia

[3] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2012年 / 90卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ruthenium complexation; formyl pyrrole; keto pyrrole; chelation; PYRROLYL LIGANDS; CHEMISTRY; SUBSTITUTION; REACTIVITY;

D O I：

10.1139/V2012-045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of the first heteroleptic pyrrolide/2,2'-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)(2)Cl-2.2H(2)O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

引用

页码：693 / 700

页数：8

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