Development of potential organic-molecule-based hydrogen storage materials: Converting C-N bond-breaking thermolysis of guanidine to N-H bond-breaking dehydrogenation

被引：6

作者：

Zhou, Xiuquan ^{[1
]}

Zhou, Wei ^{[2
]}

Udovic, Terrence J. ^{[2
]}

Yildirim, Taner ^{[2
]}

Rush, John J. ^{[2
,3
]}

Rodriguez, Efrain E. ^{[1
]}

Wu, Hui ^{[2
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[3] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 41期

关键词：

Hydrogen storage; Endothermic dehydrogenation; Crystal structure determination; Guanidine; Metal guanidinates; CRYSTAL-CHEMISTRY; HYDRIDE; AMIDE; DESTABILIZATION; BOROHYDRIDE; SODIUM; FAMILY; LINH2; LIH;

D O I：

10.1016/j.ijhydene.2016.08.129

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The small organic molecule guanidine CN3H5 can be anionized via a facile reaction with alkali-metal hydrides or amides with the formation of metal guanidinates (MCN3H4) and their guanidine adducts. The crystal structures and thermal decomposition properties of these organic-molecule-based complex hydrides were carefully investigated. Through metallation, MCN3H4 can completely preserve carbon atoms in the system and exhibit a largely improved thermal decomposition compared to CN3H5 regarding the extent of C-N bond breaking. By pairing H+ in CN3H5 or MCN3H4 with H-from metal hydrides, the resulting composite can further reduce ammonia libration and promote an endothermic dehydrogenation. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.

引用

页码：18542 / 18549

页数：8

共 4 条

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JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (51): : 13889 - 13894
[3] C-H BOND-MAKING AND BOND-BREAKING PROCESSES IN HETERONUCLEAR MONOAZADIENYL COMPLEXES - REACTIVITY OF HFERU(CO)5(RC=C(H)C(H)=N-IPR) TOWARD CO
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ORGANOMETALLICS, 1993, 12 (08) : 3187 - 3198
[4] α,β-Epoxy Esters in Multiple C-O/C-N Bond-Breaking/Formation with 2-Aminopyridines; Synthesis of Biologically Relevant (Z)-2-Methyleneimidazo[1,2-a]pyridin-3-ones
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