High alpha-regioselectivity in the rhodium-catalyzed hydroformylation of vinylpyrroles

被引：22
|
作者：
Settambolo, R [1 ]
Caiazzo, A [1 ]
Lazzaroni, R [1 ]
机构：
[1] CNR,CTR STUDI MACROMOLEC STEREORDINATE OTTICAMENTE AT,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 506卷 / 1-2期
关键词：
hydroformylation; 3-vinylpyrrole; 2-(3-pyrrolyl)propanal; rhodium; catalysis;
D O I：
10.1016/0022-328X(95)05978-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Rh-4(CO)(12)-catalyzed hydroformylation at low temperature (40 degrees C) of the 1-, 2- and 3-vinylpyrrole gives the corresponding branched aldehydes 2-(1-pyrroyl)propanal, 2-(2-pyrrolyl)propanal and 2-(3-pyrrolyl)propanal with high alpha-regioselectivity.
引用
收藏
页码：337 / 338
页数：2
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