Superior X-ray Radiation Shielding Effectiveness of Biocompatible Polyaniline Reinforced with Hybrid Graphene Oxide-Iron Tungsten Nitride Flakes

被引:46
|
作者
Hashemi, Seyyed Alireza [1 ,2 ]
Mousavi, Seyyed Mojtaba [2 ,3 ]
Faghihi, Reza [4 ,5 ]
Arjmand, Mohammad [6 ]
Rahsepar, Mansour [7 ]
Bahrani, Sonia [2 ]
Ramakrishna, Seeram [1 ]
Lai, Chin Wei [8 ]
机构
[1] Natl Univ Singapore, Ctr Nanofibers & Nanotechnol, Dept Mech Engn, Singapore 119077, Singapore
[2] Shiraz Univ Med Sci, Sch Adv Med Sci & Technol, Dept Med Nanotechnol, Shiraz 7134814336, Iran
[3] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 10607, Taiwan
[4] Shiraz Univ, Nucl Engn Dept, Shiraz 7193616548, Iran
[5] Shiraz Univ, Radiat Res Ctr, Shiraz 7193616548, Iran
[6] Univ British Columbia, Sch Engn, Kelowna, BC V1V 1V7, Canada
[7] Shiraz Univ, Sch Engn, Dept Mat Sci & Engn, Zand Blvd, Shiraz 7134851154, Iran
[8] Univ Malaya, Nanotechnol & Catalysis Res Ctr, Kuala Lumpur 50603, Malaysia
关键词
X-ray attenuation; biocompatible; polyaniline; graphene oxide; anti-bacterial; anti-fungal; LEAD-OXIDE; PHOTOELECTRON-SPECTROSCOPY; WASTE-WATER; NANOCOMPOSITES; REDUCTION; COMPOSITE; NEUTRON; FILMS; ADSORPTION; BEAM;
D O I
10.3390/polym12061407
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
X-ray radiation is a harmful carcinogenic electromagnetic source that can adversely affect the health of living species and deteriorate the DNA of cells, thus it's vital to protect vulnerable sources from them. To address this flaw, the conductive polymeric structure of polyaniline (PANi) was reinforced with diverse filler loadings (i.e., 25 wt % and 50 wt %) of hybrid graphene oxide-iron tungsten nitride (ITN) flakes toward attenuation of X-ray beams and inhabitation of microorganisms' growth. Primary characterizations confirmed the successful decoration of graphene oxide (GO) with interconnected and highly dense structure of iron tungsten nitride with a density of about 24.21 g center dot cm(-3)and reinforcement of PANi with GO-ITN. Additionally, the outcome of evaluations showed the superior performance of developed shields, where a shield with 1.2 mm thickness containing 50 wt % GO-ITN showed 131.73% increase in the electrical conductivity (compared with neat PANi) along with 78.07%, 57.12%, and 44.99% decrease in the amplitude of the total irradiated X-ray waves at 30, 40, and 60 kVp tube voltages, respectively, compared with control X-ray dosage. More importantly, the developed shields not only showed non-toxic nature and improved the viability of cells, but also completely removed the selected microorganisms at a concentration of 1000 mu g center dot mL(-1).
引用
收藏
页数:21
相关论文
共 10 条
  • [1] Superior X-ray radiation shielding of biocompatible platform based on reinforced polyaniline by decorated graphene oxide with interconnected tungsten-bismuth-tin complex
    Zarei, Maryam
    Sina, Sedigheh
    Hashemi, Seyyed Alireza
    RADIATION PHYSICS AND CHEMISTRY, 2021, 188 (188)
  • [2] Integrated polyaniline with graphene oxide-iron tungsten nitride nanoflakes as ultrasensitive electrochemical sensor for precise detection of 4-nitrophenol within aquatic media
    Hashemi, Seyyed Alireza
    Mousavi, Seyyed Mojtaba
    Bahrani, Sonia
    Ramakrishna, Seeram
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 873
  • [3] Lead oxide-decorated graphene oxide/epoxy composite towards X-Ray radiation shielding
    Hashemi, Seyyed Alireza
    Mousavi, Seyyed Mojtaba
    Faghihi, Reza
    Arjmand, Mohammad
    Sina, Sedigheh
    Amani, Ali Mohammad
    RADIATION PHYSICS AND CHEMISTRY, 2018, 146 : 77 - 85
  • [4] Novel polyethylene/tungsten oxide/bismuth trioxide/barium sulfate/graphene oxide nanocomposites for shielding against X-ray radiations
    Abdolahzadeh, T.
    Morshedian, J.
    Ahmadi, S.
    INTERNATIONAL JOURNAL OF RADIATION RESEARCH, 2023, 21 (01): : 79 - 87
  • [5] Effectiveness evaluation of self-produced micro- and nanosized tungsten materials for radiation shielding with diagnostic X-ray imaging system
    Hong, Ji Woo
    Kim, Dae Ho
    Kim, Seok Won
    Choi, Seong Hoon
    Lee, Ga-Eul
    Seo, Hyun-Kyu
    Kim, Sang-Hyun
    Lee, Youngjin
    OPTIK, 2018, 172 : 760 - 765
  • [6] Spinach leaves extract mediated synthesis of reduced graphene oxide decorated nanoferrites: Structural, X-ray/gamma ray radiation shielding and optical properties
    Reddy, B. Chinnappa
    Vidya, Y. S.
    Manjunatha, H. C.
    Manjunatha, S.
    Sridhar, K. N.
    Munirathnam, R.
    Seenappa, L.
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2024, 299
  • [7] Enhancement of nuclear radiation shielding properties of silicone rubber with γ-ray irradiation induced graphene oxide modified carbonyl iron powder hybrid fillers
    Sun, Xiaoyi
    Meng, Xianfang
    Dai, Pei
    Xu, Riwei
    Cheng, Anren
    Guo, Yueying
    Jiao, Yang
    Lu, Yongjun
    Wang, Liancai
    JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (36)
  • [8] NeemLeaves mediated green synthesis of copper ferrite decorated reduced graphene oxide nanocomposite for photoluminescence, gamma/X-ray radiation shielding, antimicrobial and anticancer properties
    Chinnappa Reddy, B.
    Manjunatha, S.
    Manjunatha, H.C.
    Vidya, Y.S.
    Sridhar, K.N.
    Seenappa, L.
    Munirathnam, R.
    Rajesh, K.
    Thirunavukkarasu, V.
    Damodara Gupta, P.S.
    Aluri, Srilakshmi
    Mohan Kumar, T.Y.
    Mahaboob Pasha, U.
    Solid State Sciences, 2022, 134
  • [9] NeemLeaves mediated green synthesis of copper ferrite decorated reduced graphene oxide nanocomposite for photoluminescence, gamma/X-ray radiation shielding, antimicrobial and anticancer properties
    Reddy, B. Chinnappa
    Manjunatha, S.
    Manjunatha, H. C.
    Vidya, Y. S.
    Sridhar, K. N.
    Seenappa, L.
    Munirathnam, R.
    Rajesh, K.
    Thirunavukkarasu, V.
    Gupta, P. S. Damodara
    Aluri, Srilakshmi
    Kumar, T. Y. Mohan
    Pasha, U. Mahaboob
    SOLID STATE SCIENCES, 2022, 134
  • [10] Development of a flexible composite based on vulcanized silicon casting with bismuth oxide and characterization of its radiation shielding effectiveness in diagnostic X-ray energy range and medium gamma-ray energies
    Demirel, Ibrahim
    Yucel, Haluk
    NUCLEAR ENGINEERING AND TECHNOLOGY, 2024, 56 (07) : 2570 - 2575