Geochemical characteristics of metabasites from different units of the Ruhla Crystalline Complex (RCC) point to Volcanic activities in different geotectonic environments, comparable with other units within the Mid-German Crystalline Rise (MGCR). Amphibolites of the Truse Formation, intercalated within staurolite-bearing metapelites and -psammites, show a subalkaline, tholeiitic character conforming to modern MOR-basalts. The geochemical signature of these amphibolites and their host rocks agree well with the geological situation known from the Horstein-Huckelheim metabasite belt (Mombris - Geiselbach formations) of the Spessart Crystalline Complex. In contrast, metabasites from the Central Gneiss Unit of the RCC, intercalated within granitic orthogneisses of Late Silurian/Early Devonian age, cover a wide range from subalkaline-andesitic to dacitic compositions. The calcalkaline character of these metabasites provides evidence for magmatism in an island-are environment, related to subduction processes after 410 but before 360 (330) Ma. Similar metabasite-orthogneiss associations are known from the Aschaffenburg-Feldkahl metabasite belt in the Spessart Crystalline Complex and from the Bollstein Odenwald. Metabasites of the Brotterode Formation of the RCC reveal MORE and island-are affinities. Due to unknown emplacement ages, a comparision of these metabasites with others within the MGCR is speculative, so far. Nevertheless, the metabasite-host rock associations of the: (i) Truse Mombris - Geiselbach (Horstein-Huckelheim) formations and (ii) the Central Gneiss Unit Haibach/Rotgneiss Complex - Bollstein Gneiss clearly indicated that the MGCR is a composite terrane of units, formed in different plate-tectonic environments at least from the Silurian onward.