Sonovoltammetric studies on copper in buffered alkaline solution

The effect of ultrasound on the voltammetry of copper in alkaline solution is reported. At pH 7 the electrode surface remains active after scanning to ca. +1.0 V (vs. SCE) and the effects of ultrasound show the expected substantial enhancement in limiting current due to improved mass transport under ultrasound. However at pH 9, whereas the silent scan is only slightly altered in gross detail from that obtained at pH 7, the sonicated scan is significantly different. This shows the expected current increase only up until ca. +0.6 V (vs. SCE), where there is a substantial loss of current showing a passivation phenomenon that is enhanced by ultrasound. In addition, during the reverse (reduction) scan under ultrasound an anodic peak appears. This suggests reactivation of the electrode during the cathodic sweep, possibly by reductive removal of a transient species from the electrode/(hydr)oxide interface at a potential where oxidation still occurs. Increasing the pH to 11 further shifts the cathodic peaks in the silent voltammogram. (C) 2004 Published by Elsevier B.V.