The valence states of nickel, tin, and sulfur in the ternary chalcogenide Ni3Sn2S2-XPS, 61Ni and 119Sn Mossbauer investigations, and band structure calculations

被引：0
|
作者：
Gütlich, P
Range, KJ
Felser, C
Schultz-Münzenberg, C
Tremel, W
Walcher, D
Waldeck, M
机构：
[1] Univ Mainz, Inst Anorgan & Analyt Chem, D-55099 Mainz, Germany
[2] Univ Regensburg, Inst Anorgan Chem, D-55099 Regensburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 16期
关键词：
density functional calculations; Moessbauer spectroscopy; photoelectron spectroscopy; solid-state structures;
D O I：
10.1002/(SICI)1521-3773(19990816)38:16<2381::AID-ANIE2381>3.0.CO;2-L
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hitherto controversial valence states of nickel and tin in the ternary chalcogenide Ni3Sn2S2 (see structure) have been determined by photoelectron and Mossbauer spectroscopy (61Ni, 119Sn). Results from hand structure calculations confirmed that this shandite phase is a metal and that the approximate distribution of the valence electrons is (Ni0)3(Sn(1)(II))(Sn(2)(II))(S(II-))2.
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收藏
页码：2381 / 2384
页数：4
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