Synthesis of Hexa(furan-2-yl)benzenes and Their π-Extended Derivatives

被引：23
|
作者：
Mitsudo, Koichi [1 ]
Harada, Jyunji [1 ]
Tanaka, Yo [1 ]
Mandai, Hiroki [1 ]
Nishioka, Chie [1 ]
Tanaka, Hideo [1 ]
Wakamiya, Atsushi [2 ]
Murata, Yasujiro [2 ]
Suga, Seiji [1 ]
机构：
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biotechnol, Kita Ku, Okayama 7008530, Japan
[2] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 06期
关键词：
CATALYZED 2+2+2 CYCLOADDITION; FIELD-EFFECT TRANSISTORS; ELECTROCHEMICAL PROPERTIES; ALPHA-OLIGOFURANS; FURAN MOIETY; EFFICIENT; HOLE; SEMICONDUCTOR; CONSTRUCTION; MOLECULES;
D O I：
10.1021/jo302652r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first synthesis of hexa(furan-2-yl)benzene derivatives is described. The RhCl3/i-Pr2NEt-catalyzed cyclotrimerization of di(furan-2-yl)acetylenes was an effective method for constructing hexa(furan-2-yl)benzene derivatives in good yields. Their pi-extended derivatives were also synthesized by Suzuki-Miyaura coupling between hexakis(5-Bpinfuran-2-yl)benzene (Bpin = (pinacolato)boryl) and several aryl iodides.
引用
收藏
页码：2763 / 2768
页数：6
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