Pnictide-Capped Butterfly Cluster in the Crystal Structure of Nb4PnX11 (Pn = N, P; X = Cl, Br, I)

被引：2

作者：

Stroebele, Markus ^{[1
]}

Oeckler, Oliver ^{[2
,3
]}

Thelen, Michael ^{[4
]}

Fink, Reinhold F. ^{[4
]}

Krishnamurthy, Arun ^{[5
]}

Kroeker, Scott ^{[5
]}

Meyer, Hans-Juergen ^{[1
]}

机构：

[1] Eberhard Karls Univ Tubingen, Inst Inorgan Chem, Sect Solid State & Theoret Inorgan Chem, D-72076 Tubingen, Germany

[2] Univ Leipzig, Inst Mineral Crystallog & Mat Sci, D-04275 Leipzig, Germany

[3] Univ Leipzig, Fac Chem & Mineral, D-04275 Leipzig, Germany

[4] Eberhard Karls Univ Tubingen, Inst Phys & Theoret Chem, D-72076 Ribingen, Germany

[5] Univ Manitoba, Dept Chem, Winnipeg, MB R3T 2N2, Canada

来源：

INORGANIC CHEMISTRY | 2022年

关键词：

SHIELDING TENSORS; EXCHANGE-ENERGY; NIOBIUM; CHEMISTRY; COMPOUND; TANTALUM; HALIDES; CHARGE;

D O I：

10.1021/acs.inorgchem.2c02646

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Niobium pnictide halides Nb4PnX11 (Pn = N, P; X = Cl, Br, I) are reported with their average crystal structures. Individual pnictide-capped butterfly cluster cores [Nb4P] in the structure are interconnected into two-dimensional layers, with their electronic and magnetic properties being analyzed.

引用

页码：17599 / 17608

页数：10

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