Effect of γ-irradiation on the physical and mechanical properties of chitosan powder

In this study, locally produced chitosan powder was irradiated with pre-determined doses of gamma-ray (Co-60) of 10 kGy, 25 kGy, 50 kGy and 100 kGy respectively. The properties of both chitosan powder and the chitosan him were examined and compared with unradiated chitosan. Physical characteristic of the irradiated powder and film was studied using stereo microscope. It was observed that the gamma-ray induces a noticeable colour tone intensity change to the chitosan. Further investigation using Fourier Transformed Infrared Spectroscopy (FT-IR) analysis has confirmed that the chain scission reaction was occurred as a result of gamma-ray exposure through the depolymerization mechanisms. Interestingly, the degree of deacetylation (DD) of chitosan measured using FT-IR showed a negligible effect due to the exposure of gamma-ray radiation. Further investigation on the viscosity average molecular weight (M-v) showed a reduction of M-v from 577 kD of pure chitosan to 458 kD, 242 kD, 159 kD and 106 kD for 10 kGy, 25 kGy. 50 kGy and 100 kGy of gamma-radiated chitosan respectively. In addition, the tensile strength and elongation at break showed a similar decreasing trend with increasing dosage of gamma-ray. (c) 2008 Elsevier B.V. All rights reserved.