The reactivity of tert-butoxyl radicals in reactions of hydrogen abstraction and β-elimination

被引：6

作者：

Opeida, IA ^{[1
]}

Dmitruk, AF ^{[1
]}

Zarechnaya, OM ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LM Litvinenko Inst Physicoorgan & Coal Chem, UA-340114 Donetsk, Ukraine

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 02期

关键词：

tert-butoxyl radical; transition state; reactivity; semiempirical method AM1;

D O I：

10.1023/A:1009570032394

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transition states of competing reactions of abstraction of the H atom from hydrocarbon molecules by tert-butoxyl radical and its beta-elimination were studied by the semiempirical quantum-chemical AM1 method. The calculated activation enthalpy and entropy of these reactions correlate with the experimental values. A correlation between the reactivity in homolytic hydrogen abstraction and the parameters of the chemical structure of the reactants was found.

引用

页码：241 / 244

页数：4

共 50 条

[1] The reactivity of tert-butoxyl radicals in reactions of hydrogen abstraction and β-elimination
I. A. Opeida
A. F. Dmitruk
O. M. Zarechnaya
Russian Chemical Bulletin, 2001, 50 : 241 - 244
[2] REACTIVITY OF POLYHYDRIC ESTERS AND ALCOHOLS IN REACTIONS WITH TERT-BUTOXYL RADICALS
POZDEEVA, NN
GERCHIKOV, AY
SIRAEVA, IN
MARTEMYANOV, VS
KINETICS AND CATALYSIS, 1986, 27 (04) : 686 - 690
[3] THE REACTIONS OF TERT-BUTOXYL WITH UNSATURATED-HYDROCARBONS - STRUCTURE AND REACTIVITY OF ALLYLIC RADICALS
CUTHBERTSON, MJ
RIZZARDO, E
SOLOMON, DH
AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (10) : 1957 - 1973
[4] HYDROGEN-ATOM ABSTRACTION FROM POLYSTYRENE BY TERT-BUTOXYL RADICALS, STUDIED BY SPIN TRAPPING - EFFECT OF CONFORMATION ON REACTIVITY
OHTO, N
NIKI, E
KAMIYA, Y
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (11): : 1416 - 1418
[5] A KINETIC-STUDY OF THE REACTIONS OF TERT-BUTOXYL WITH ALKENES - HYDROGEN ABSTRACTION VS ADDITION
WONG, PC
GRILLER, D
SCAIANO, JC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) : 5106 - 5108
[6] AN ESR STUDY OF REACTIONS OF TERT-BUTOXYL RADICALS WITH AMINOPHOSPHINES
DENNIS, RW
ROBERTS, BP
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 43 (01) : C2 - +
[7] THE SUBSTITUENT EFFECT ON THE REACTIVITY OF SILANES TOWARDS TERT-BUTOXYL RADICALS
CHATGILIALOGLU, C
ROSSINI, S
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1988, (02): : 298 - 300
[8] REACTION OF TERT-BUTOXYL RADICALS WITH DIBORANE
INGOLD, KU
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1973, (04): : 420 - 424
[9] Kinetics of abstraction reactions of tert-butoxyl radicals with cyclohexane and methyl-substituted cyclohexanes in the gas phase
1600, (87):
[10] REACTIVITY OF TERT-BUTOXYL RADICALS TOWARDS SUBSTITUTED INDOLE-DERIVATIVES
ENCINAS, MV
LISSI, EA
MAJMUD, C
OLEA, AF
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1991, 23 (09) : 761 - 766

← 1 2 3 4 5 →