Study of the catalytic activity of aluminum, zirconium and cerium pillared clays in the synthesis of 2,2-dimethyl-1,3-dioxolane

被引：8
|
作者：
Mnasri, Saida [1 ]
Besbes, Neji [1 ]
Frini-Srasra, Najoua [2 ]
Srasra, Ezzeddine [1 ]
机构：
[1] Ctr Natl Rech Sci Mat, Lab Physicochim Mat Mineriaux & Leurs Applicat, Soliman 8027, Tunisia
[2] Fac Sci Tunis, Dept Chim, Tunis 1060, Tunisia
来源：
COMPTES RENDUS CHIMIE | 2012年 / 15卷 / 05期
关键词：
Acetalyzation; Bronsted and Lewis acid sites; Dioxolane; Heterogeneous catalyst; Pillared clay; AL-CE-FE; MONTMORILLONITE;
D O I：
10.1016/j.crci.2012.03.002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The purified Tunisian clay G and the commercialized American clay W were pillared with zirconium, aluminum and mixed pillars zirconium-aluminum, cerium-zirconium, cerium-aluminum, and cerium-zirconium-aluminum. These different clays were used in the synthesis of 2,2-dimethyl-1,3-dioxolane 3 by acetalyzation of acetone 2 with ethylene glycol 1 under autogenously pressure and without solvent. Results indicate that the yield of product 3 depends of the nature and the acidity of the clay used and the time of reaction. (C) 2012 Academic des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：437 / 443
页数：7
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