Synthesis of PVP/IO-MMT Nanocomposite using Industrial Organic Montmorillonite

被引:4
|
作者
Gao, Dangge [1 ]
Ma, Jianzhong [1 ]
Lu, Hua [1 ]
Chu, Yun [1 ]
Yang, Zongsui [1 ]
机构
[1] Shaanxi Univ Sci & Technol, Coll Resource & Environm, Xian 710021, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
industrial organic montmorillonite; dispersant; surfactants;
D O I
10.1177/0021998308096503
中图分类号
TB33 [复合材料];
学科分类号
摘要
Industrial organic montmorillonite (IO-MMT) was characterized by X-ray diffraction (XRD) and thermogravimetry (TG). The results indicate that IO-MMT could prepare nanocomposite directly in theory. As dispersants, different nonionic surfactants were used to disperse IO-MMT. The result shows that nonionic surfactant TO-10 was selected as optimum dispersant. Then, vinyl polymer/industrial organic montmorillonite nanocomposite (PVP/IO-MMT) was prepared by vinyl polymer (PVP) and IO-MMT which dispersed in nonionic surfactant TO-10. The structure of PVP/IO-MMT nanocomposite was characterized by XRD and TEM. The result of XRD shows that the basal spacing d value of nanocomposite is 3.53 nm. The result of TEM indicates that composite was intercalated nanocomposite. Finally, PVP/IO-MMT was applied in the leather making process to examine its properties. The pickled sheepskin was tanned with 6% PVP/IO-MMT associated with 2% chromate, the shrinkage temperature of leather can be raised to 88 degrees C. The application results show that it is an effective way to decrease the use of chromate for nanocomposites.
引用
收藏
页码:2805 / 2814
页数:10
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