Top-Seeded Single-Crystal Growth, Structure, and Physical Properties of Polar LiCrP2O7

被引:12
|
作者
Pachoud, Elise [1 ]
Zhang, Weiguo [1 ]
Tapp, Joshua [1 ]
Liang, Kao-Chen [2 ,3 ]
Lorenz, Bernd [2 ,3 ]
Chu, Paul C. W. [2 ,3 ]
Halasyamani, P. Shiv [1 ,4 ]
机构
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Univ Houston, Houston Sci Ctr, Texas Ctr Superconduct, Houston, TX 77204 USA
[3] Univ Houston, Houston Sci Ctr, Dept Phys, Houston, TX 77204 USA
[4] Aalto Univ, Dept Chem, Espoo 02150, Finland
基金
美国国家卫生研究院;
关键词
RAY-POWDER DIFFRACTION; NEUTRON-DIFFRACTION; LIFEP2O7; MODEL; FIELD;
D O I
10.1021/cg401442r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single crystals of polar LiCrP2O7 were grown by using a top-seeded solution growth method. In addition to the crystal structure, detailed magnetic measurements reveal anisotropic magnetic behavior with a spin-flop transition. Piezoelectric, polarization, and heat capacity measurements were also taken on the single crystals. Powder second-harmonic generating measurements, using 1064 nm radiation, revealed type 1 phase-matching behavior with an efficiency of approximately 30 X alpha-SiO2.
引用
收藏
页码:5473 / 5480
页数:8
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