Recycling the product of thermal transformation of cement-asbestos for the preparation of calcium sulfoaluminate clinker

被引:33
|
作者
Viani, Alberto [1 ]
Gualtieri, Alessandro F. [1 ]
机构
[1] Univ Modena & Reggio Emilia, Dipartimento Sci Chim & Geol, I-41121 Modena, Italy
关键词
Cement-asbestos; Recycling; Sulfoaluminate; Rietveld method; Amorphous; POWDER DIFFRACTION; CRYSTAL-CHEMISTRY; BELITE CEMENT; INERTIZATION; DECOMPOSITION; PERFORMANCE; KINETICS;
D O I
10.1016/j.jhazmat.2013.06.020
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
According to recent resolutions of the European Parliament (2012/2065(INI)), the need for environmentally friendly alternative solutions to landfill disposal of hazardous wastes, such as asbestos-containing materials, prompts their recycling as secondary raw materials (end of waste concept). In this respect, for the first time, we report the recycling of the high temperature product of cement-asbestos, in the formulation of calcium sulfoaluminate cement clinkers (novel cementitious binders designed to reduce CO2 emissions), as a continuation of a previous work on their systematic characterization. Up to 29 wt% of the secondary raw material was successfully introduced into the raw mix. Different clinker samples were obtained at 1250 degrees C and 1300 degrees C, reproducing the phase composition of industrial analogues. As an alternative source of Ca and Si, this secondary raw material allows for a reduction of the CO2 emissions in cement production, mitigating the ecological impact of cement manufacturing, and reducing the need for natural resources. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:813 / 818
页数:6
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