Synthesis and characterization of a novel open-framework nickel zinc phosphite with intersecting three-dimensional 16-ring channels

被引：48
|
作者：
Lin, ZE
Zhang, J
Zheng, ST
Yang, GY [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Coordinat & Hydrothermal Chem Grp, Fujian 350002, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2004年 / 14卷 / 10期
关键词：
D O I：
10.1039/b402321h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn-2(HPO3)(3) (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open-framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni-2(DETA)(2)(H2O)(2)O-2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.
引用
收藏
页码：1652 / 1655
页数：4
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