The luminescence spectrum of the uranyl ion contains no evidence of strong vibronic anharmonicity in the first electronic excited state

被引：5
|
作者：
Denning, R. G. [1 ]
机构：
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
来源：
JOURNAL OF LUMINESCENCE | 2008年 / 128卷 / 11期
关键词：
uranyl; luminescence spectrum; vibronic coupling; anharmonicity;
D O I：
10.1016/j.jlumin.2008.04.006
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The work of Liu and Vikhnin [Chem. Phys. Lett. 437 (2007) 56] on anharmonic charge-transfer vibronic states in uranyl compounds is examined critically. It is concluded that there is currently no experimental evidence to justify the use of a phenomenological model of anharmonic vibronic coupling in these systems. (C) 2008 Elsevier B.V. All rights reserved.
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页码：1745 / 1747
页数：3
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